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  • Design and synthesis of beta-methoxyacrylate analogues via click chemistry and biological evaluations.

Design and synthesis of beta-methoxyacrylate analogues via click chemistry and biological evaluations.

Bioorganic & medicinal chemistry letters (2007-02-16)
Hao Chen, Janet L Taylor, Suzanne R Abrams
ABSTRACT

A library of potential antifungal triazole-modified beta-methoxyacrylate analogues was designed and synthesized via a Cu(I)-catalyzed 1,3-dipolar alkyne-azide coupling reaction or 'click chemistry'. Subsequent biological screening revealed that some compounds displayed low to moderate antifungal activity toward pathogenic fungi and low phytotoxicity.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
1-Ethynyl-1-cyclohexanol, ≥99%
Sigma-Aldrich
Phenylacetylene, 98%
Sigma-Aldrich
Ethynyl p-tolyl sulfone, 98%