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  • Unprecedented Cu(I)-catalyzed microwave-assisted three-component coupling of a ketone, an alkyne, and a primary amine.

Unprecedented Cu(I)-catalyzed microwave-assisted three-component coupling of a ketone, an alkyne, and a primary amine.

Organic letters (2010-05-06)
Olga P Pereshivko, Vsevolod A Peshkov, Erik V Van der Eycken
ABSTRACT

An efficient, microwave-assisted Cu(I)-catalyzed one-pot coupling of a ketone, an alkyne, and a primary amine (KA(2) coupling) is described, giving access to secondary propargylamines.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Propargylamine, 98%
Sigma-Aldrich
Propargylamine hydrochloride, 95%