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  • The preparation and characterization of non-covalently functionalized graphene.

The preparation and characterization of non-covalently functionalized graphene.

Journal of nanoscience and nanotechnology (2012-04-25)
Nantao Hu, Rungang Gao, Yanyan Wang, Yanfang Wang, Jing Chai, Zhi Yang, Eric Siu-Wai Kong, Yafei Zhang
ABSTRACT

Recently, much work has focused on the exfoliation of graphene through a combination of oxidation and sonication procedures, followed by reduction through chemical methods. We demonstrated that the individual graphene oxide sheets can be readily reduced by using phenolphthalin as both reducing agent and stabilizer. The obtained non-covalently functionalized chemically reduced graphene oxide (CRG) can be dispersed in organic solvents very well, such as alcohol, N,N-dimethylformamide, N,N-Dimethylacetamide, N-methyl-2-pyrrolidone, etc., which can give practical applications in large scale production of oil dispersible graphene and have a potential in polymer nanocomposites fabrication.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
Phenolphthalein, ACS reagent
Sigma-Aldrich
Phenolphthalein, JIS special grade, ≥98.0%
Sigma-Aldrich
Phenolphthalein solution, 1 % (w/v), pH 7.8-10.0
Sigma-Aldrich
Phenolphthalein solution, 0.1 % (w/v), pH 7.8-10.0
Sigma-Aldrich
Phenolphthalein, SAJ first grade, ≥97.0%
Sigma-Aldrich
Phenolphthalein solution, 0.04 % (w/v), pH 7.8-10.0
Sigma-Aldrich
Phenolphthalein solution, 0.5 wt. % in ethanol: water (1:1)