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  • Covalent modification of a metal-organic framework with isocyanates: probing substrate scope and reactivity.

Covalent modification of a metal-organic framework with isocyanates: probing substrate scope and reactivity.

Chemical communications (Cambridge, England) (2008-07-18)
Emily Dugan, Zhenqiang Wang, Marilyn Okamura, Annette Medina, Seth M Cohen
ABSTRACT

Isoreticular metal-organic framework-3 (IRMOF-3) has been postsynthetically modified with isocyanates to generate unprecedented, microporous urea-functionalized frameworks.

MATERIALS
Product Number
Brand
Product Description

Sigma-Aldrich
(Trimethylsilyl)isocyanate, 85%
Sigma-Aldrich
tert-Butyl isocyanate, 97%