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Ruthenium-catalyzed atom transfer radical addition reactions.

Chimia (2012-08-09)
Kay Severin
PMID22871280
ABSTRACT

Certain ruthenium complexes are potent catalysts for atom transfer radical addition (ATRA) and cyclization (ATRC) reactions, in particular if they are used in conjunction with reducing agents such as magnesium. This short overview summarizes recent developments in this area with special focus on contributions from our laboratory.

MATERIALS
Product Number
Brand
Product Description
326712
Sigma-Aldrich
Ruthenium black
209694
Sigma-Aldrich
Ruthenium, powder, −200 mesh, 99.9% trace metals basis
545023
Sigma-Aldrich
Ruthenium, powder, 99.99% trace metals basis
GF85328523
Ruthenium, Ruthenium, pellets, 2.5g, max. size 10mm, 99.9%
GF01141333
Ruthenium, Ruthenium, microfoil, disks, 10mm, thinness 0.1μm, specific density 122μg/cm2, permanent mylar 3.5μm support, 99.9%
GF07844249
Ruthenium, Ruthenium, foil, 10x10mm, thickness 1.0mm, 99.9%
GF58059120
Ruthenium, Ruthenium, foil, 25x25mm, thickness 1.0mm, 99.9%
GF65001440
Ruthenium, Ruthenium, pellets, 5g, max. size 10mm, 99.9%
GF86442183
Ruthenium, Ruthenium, rod, 12.7mm, diameter 12.7mm, 99.9%
GF83525193
Ruthenium, Ruthenium, bar, 25mm x 2mm x 2mm, 99.9%
GF40738260
Ruthenium, Ruthenium, foil, 6x6mm, thickness 1.0mm, 99.9%
GF60948658
Ruthenium, Ruthenium, microfoil, disks, 10mm, thinness 0.025μm, specific density 30.5μg/cm2, permanent mylar 3.5μm support, 99.9%
GF50816998
Ruthenium, Ruthenium, bar, 50mm x 2mm x 2mm, 99.9%