- Recent advances in homogeneous nickel catalysis.
Recent advances in homogeneous nickel catalysis.
Nature (2014-05-16)
Sarah Z Tasker, Eric A Standley, Timothy F Jamison
PMID24828188
ABSTRACT
Tremendous advances have been made in nickel catalysis over the past decade. Several key properties of nickel, such as facile oxidative addition and ready access to multiple oxidation states, have allowed the development of a broad range of innovative reactions. In recent years, these properties have been increasingly understood and used to perform transformations long considered exceptionally challenging. Here we discuss some of the most recent and significant developments in homogeneous nickel catalysis, with an emphasis on both synthetic outcome and mechanism.
MATERIALS
Product Number
Brand
Product Description
Sigma-Aldrich
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-(diphenylphosphino)ferrocenyl]ethylditertbutylphosphine]nickel(II), ≥95%
Sigma-Aldrich
Chloro(4-cyanophenyl)[(R)-1-[(S)-2-[bis(4-fluorophenyl]phosphino]ferrocenyl]ethyldi-tert-butylphosphine]nickel(II), ≥95%
Nickel, foil, not light tested, 100x100mm, thickness 0.004mm, hard, 99%
Nickel, foil, light tested, 25x25mm, thickness 0.009mm, 99.95%
Nickel, foil, not light tested, 25x25mm, thickness 0.001mm, 99.95%
Nickel, foil, not light tested, 100x100mm, thickness 0.002mm, 99.95%
Nickel, foil, not light tested, 25x25mm, thickness 0.0005mm, temporary acrylic support, 99.95%
Nickel, foil, light tested, 100x100mm, thickness 0.007mm, 99.95%
Nickel, wire reel, 10m, diameter 0.25mm, hard, 99.98%
Nickel, wire reel, 100m, diameter 0.25mm, hard, 99.98%
Nickel, foil, 4mm disks, thickness 0.009mm, 99.95%
Nickel, foil, 0.5m coil, thickness 0.0075mm, 99.9%
Nickel, tube, 500mm, outside diameter 1.5mm, inside diameter 1.2mm, wall thickness 0.15mm, hard, 99.5%
Nickel, foil, not light tested, 25x25mm, thickness 0.003mm, 99.95%
Nickel, rod, 1000mm, diameter 3.0mm, 99%
Nickel, foil, 25x25mm, thickness 0.30mm, as rolled, 99.98%
Nickel, foil, light tested, 50x50mm, thickness 0.05mm, 99.9%
Nickel, mesh, 30x30mm, nominal aperture 0.34mm, thickness 0.025mm, wire diameter 0.041mm, 70 wires/inch, open area 80%, electro-formed mesh, 99.9%
Nickel, foil, light tested, 300x300mm, thickness 0.03mm, 99.9%
Nickel, foil, 8mm disks, thickness 0.25mm, as rolled, 100%
Nickel, foil, 8mm disks, thickness 0.15mm, annealed, 99%
Nickel, foil, 10mm disks, thickness 0.5mm, as rolled, 100%
Nickel, foil, 10mm disks, thickness 0.05mm, as rolled, 99.99+%
Nickel, foil, 1m coil, thickness 0.25mm, annealed, 99%
Nickel, foil, 1m coil, thickness 0.02mm, 99.9%
Nickel, foil, 10mm disks, thickness 0.125mm, as rolled, 100%
Nickel, sphere, 100pcs, diameter 0.76mm, precision sphere grade 200, 99%
Nickel, foil, 8mm disks, thickness 0.03mm, 99.9%
Nickel, foil, light tested, 25x25mm, thickness 0.05mm, as rolled, 99.98%