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Sigma-Aldrich

1-Bromo-2-methylnaphthalene

technical grade, 90%

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About This Item

Linear Formula:
CH3C10H6Br
CAS Number:
2586-62-1
Molecular Weight:
221.09
Beilstein/REAXYS Number:
2042531
EC Number:
219-966-1
MDL number:
MFCD00003871
UNSPSC Code:
12352100
PubChem Substance ID:
24847598
NACRES:
NA.22

grade

technical grade

Quality Level

100

assay

90%

form

liquid

refractive index

n20/D 1.648 (lit.)

bp

296 °C (lit.)

density

1.418 g/mL at 25 °C (lit.)

SMILES string

Cc1ccc2ccccc2c1Br

InChI

1S/C11H9Br/c1-8-6-7-9-4-2-3-5-10(9)11(8)12/h2-7H,1H3

InChI key

CMIMBQIBIZZZHQ-UHFFFAOYSA-N

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General description

Dynamic phosphorescence quenching of 1-bromo-2-methylnaphthalene without deoxygenation has been used for selective sensing of Cu(II) at ngml-1 levels. It undergoes asymmetric cross-coupling reaction with its corresponding Grignard reagent using a nickel catalyst to form non-racemic 2,2′-dimethyl-1,1′-binaphthyl.

Application

1-Bromo-2-methylnaphthalene was used as test compound in determination of halogenated hydrocarbons at trace levels by supercritical fluid chromatography-microwave-induced plasma mass spectrometry.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis of chiral binaphthalenes using the asymmetric Suzuki reaction.
Cammidge AN and Crepy KVL.
Tetrahedron, 60(20), 4377-4386 (2004)
N A Vinokurova
Voprosy onkologii, 21(3), 19-24 (1975-01-01)
The author presents an analysis of the results of the combination chemotherapy with natulan, vincristin, novembichine and prednisolone in 43 patients showing generalized lymphogranulomatosis, mainly with recurrences following radiation and chemotherapy with different antitumor substances. The results of the combination
Determination of halogenated compounds with supercritical fluid chromatography-microwave-induced plasma mass spectrometry.
Olson LK and Caruso JA.
Journal of Analytical Atomic Spectrometry, 7(6), 993-998 (1992)

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