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Sigma-Aldrich

Bis(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate

Synonym(s):

Rhodium(I) tetrafluoroborate 1,5-Cyclooctadiene complex

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About This Item

Empirical Formula (Hill Notation):
C16H24BF4Rh
CAS Number:
35138-22-8
Molecular Weight:
406.07
MDL number:
MFCD00075045
UNSPSC Code:
12352300
PubChem Substance ID:
57647189
NACRES:
NA.22

composition

carbon content, 45.7-49.0%

Quality Level

100

reaction suitability

core: rhodium
reagent type: catalyst

mp

~190 °C (dec.)

SMILES string

[Rh+].F[B-](F)(F)F.C1CC=CCCC=C1.C2CC=CCCC=C2

InChI

1S/2C8H12.BF4.Rh/c2*1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h2*1-2,7-8H,3-6H2;;/q;;-1;+1/b2*2-1-,8-7-;;

InChI key

NBGSCPNNKGVTKU-QMDOQEJBSA-N

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Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

Other Notes

Rhodium complex employed for preparing cationic COD-Rh complexes with phosphine ligands, e.g. for enantioselective hydrogenation; Hydrosilylation

pictograms

Exclamation markHealth hazard
GHS07,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Eye Irrit. 2 - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT SE 3

target_organs

Respiratory system

Storage Class

4.1B - Flammable solid hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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R. Takeuchi et al.
The Journal of Organic Chemistry, 60, 3045-3045 (1995)
I. Ojima et al.
Tetrahedron, 45, 6901-6901 (1989)
M. Sawamura et al.
Journal of the American Chemical Society, 117, 9602-9602 (1995)
U. Nagel et al.
Chemische Berichte, 119, 3326-3326 (1986)

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