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185841

Sigma-Aldrich

Dicyclohexylamine

99%

Synonym(s):

Aminodicyclohexane, Bis(cyclohexyl)amine, Dodecahydrodiphenylamine, N,N-Dicyclohexylamine, N-Cyclohexylcyclohexanamine

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About This Item

Linear Formula:
(C6H11)2NH
CAS Number:
101-83-7
Molecular Weight:
181.32
Beilstein/REAXYS Number:
605923
EC Number:
202-980-7
MDL number:
MFCD00011658
UNSPSC Code:
12352100
eCl@ss:
39030438
PubChem Substance ID:
24851183
NACRES:
NA.22

vapor density

6 (vs air)

Quality Level

200

vapor pressure

12 mmHg ( 37.7 °C)

assay

99%

form

liquid

refractive index

n20/D 1.484 (lit.)

bp

117-120 °C/10 mmHg
256 °C (lit.)

mp

−2 °C (lit.)

solubility

organic solvents: soluble
water: very slightly soluble

density

0.912 g/mL at 20 °C (lit.)

SMILES string

C1CCC(CC1)NC2CCCCC2

InChI

1S/C12H23N/c1-3-7-11(8-4-1)13-12-9-5-2-6-10-12/h11-13H,1-10H2

InChI key

XBPCUCUWBYBCDP-UHFFFAOYSA-N

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Application

Dicyclohexylamine was used to constitute ionic liquid matrices for bacterial analysis in matrix assisted laser desorption/ionisation mass spectrometry. It was used to develop a new palladium catalyst for Suzuki coupling reaction of aryl bromides with boronic acids. It was used as extractant in determination of gold(III) by dispersive liquid-liquid microextraction and electrothermal atomic absorption spectrometry.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Skin Corr. 1B

wgk_germany

WGK 2

flash_point_f

204.8 °F

flash_point_c

96 °C

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Shigehiro Kagaya et al.
Talanta, 80(3), 1364-1370 (2009-12-17)
A combined method with dispersive liquid-liquid microextraction (DLLME) and electrothermal atomic absorption spectrometry (ETAAS) has been developed for determining gold(III). Dicyclohexylamine, a new extractant for gold(III), showed excellent performance in DLLME. Acetone was indispensable to the quantitative extraction of gold(III)
Bin Tao et al.
The Journal of organic chemistry, 69(13), 4330-4335 (2004-06-19)
A new palladium catalyst (DAPCy) made from Pd(OAc)(2) and commercially available, inexpensive dicyclohexylamine has been developed for the Suzuki coupling reaction of aryl bromides with boronic acids to give the coupling products in good to high yields. The air-stable catalyst
R H Davis et al.
Proceedings of the National Academy of Sciences of the United States of America, 82(12), 4105-4109 (1985-06-01)
We wished to identify metabolic signals governing changes in ornithine decarboxylase (L-ornithine carboxy-lyase, EC 4.1.1.17) activity in Neurospora crassa. By manipulations of the ornithine supply and by the use of inhibitors of the polyamine pathway, we found that spermidine negatively
Ehsan Partovi et al.
Annals of work exposures and health, 63(7), 797-805 (2019-07-07)
This research develops a rapid method for sampling and analysis of maleic anhydride (MA) in air using a one-step hollow fiber (HF) membrane in the liquid phase followed by high-performance liquid chromatography. A sampling chamber was prepared for sampling of
S J Pietr et al.
Mycoses, 32(7), 359-361 (1989-07-01)
Inhibitory doses (ID50) of phenols complexed with dicyclohexylamine are lower (21.4-47.7%) than the inhibitory doses of free phenols. This is demonstrated in vitro by experiments with Aspergillus oryzae and Penicillium expansum on solid medium.
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