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195332

Sigma-Aldrich

1-Bromotetradecane

97%

Synonym(s):

Myristyl bromide, Tetradecyl bromide

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About This Item

Linear Formula:
CH3(CH2)13Br
CAS Number:
112-71-0
Molecular Weight:
277.28
Beilstein/REAXYS Number:
1742640
EC Number:
203-999-3
MDL number:
MFCD00000228
UNSPSC Code:
12352100
PubChem Substance ID:
24851686
NACRES:
NA.22

Quality Level

200

assay

97%

form

liquid

refractive index

n20/D 1.460 (lit.)

bp

175-178 °C/20 mmHg (lit.)

mp

5-6 °C (lit.)

density

0.932 g/mL at 25 °C (lit.)

SMILES string

CCCCCCCCCCCCCCBr

InChI

1S/C14H29Br/c1-2-3-4-5-6-7-8-9-10-11-12-13-14-15/h2-14H2,1H3

InChI key

KOFZTCSTGIWCQG-UHFFFAOYSA-N

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Application

1-Bromotetradecane was used in the synthesis of:
  • tetradecylferrocene
  • cationic and zwitterionic gemini surfactants
  • metallomesogenic polymers based on bis[η1(N)-3,4-dialkyloxybenzylidene-4′-dodecyloxyaniline]dichloropalladium(II) with octyl, decyl, dodecyl, tetradecyl and hexadecyl alkyl groups
  • 9-tetradecylcarbazole

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Atakilt Abebe et al.
Bioinorganic chemistry and applications, 2018, 8097483-8097483 (2018-08-18)
New organic salts were synthesized by quaternizing 1,10-phenanthroline using 1-bromotetradecane. The first step yielded an organic salt of formula [C26H37N2]Br. Anion exchange reaction using Li[(CF3SO2)2N] resulted in a more stable salt of formula [C26H37N2][(CF3SO2)2N]. The organic salts were investigated by
R Hernández-Bravo et al.
The journal of physical chemistry. B, 122(15), 4325-4335 (2018-03-29)
A combined study for understanding the molecular interactions of asphaltenes with molecular species such as ionic liquids (ILs) comprised experimental measurements and computational numerical simulation calculations, using density-functional theory (DFT) with dispersion corrections, molecular dynamics (MD) calculations, and experimental rheological
Novel Metallomesogenic Polymers Derived from ? 1-Benzylideneaniline Palladium (II) Complex.
Lee M, et al.
Macromolecules, 32(8), 2777-2782 (1999)
Katrin Wedeking et al.
Langmuir : the ACS journal of surfaces and colloids, 22(7), 3161-3165 (2006-03-22)
Tetradecylferrocene (4, Fc-(CH2)13CH3) was synthesized via lithiation of ferrocene by treatment with tert-butyl lithium, followed by alkylation with 1-bromotetradecane. Complex 4 forms a physisorbed ordered molecular monolayer on the surface of highly oriented pyrolytic graphite (HOPG) that was analyzed by
Preparation of a Carbazole-Based Macrocycle Via Precipitation-Driven Alkyne Metathesis.
Zhang W, et al.
Organic Syntheses, 177-191 (2007)
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