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200913

Sigma-Aldrich

Potassium hexafluorophosphate

≥99%

Synonym(s):

Monopotassium hexafluorophosphate

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About This Item

Linear Formula:
KPF6
CAS Number:
17084-13-8
Molecular Weight:
184.06
EC Number:
241-143-0
MDL number:
MFCD00011412
UNSPSC Code:
12352302
PubChem Substance ID:
24851982
NACRES:
NA.23

Quality Level

200

assay

≥99%

form

solid

technique(s)

ion chromatography: suitable

mp

575 °C (lit.)

density

2.75 g/mL at 25 °C (lit.)

SMILES string

[K+].F[P-](F)(F)(F)(F)F

InChI

1S/F6P.K/c1-7(2,3,4,5)6;/q-1;+1

InChI key

YZDGRYDIGCWVND-UHFFFAOYSA-N

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Application

Potassium hexafluorophosphate can be used as an electrolyte additive to improve the:
  • Electrochemical performance of an anode-free lithium metal battery.
  • Cycling stability and Li Coulombic efficiency of lithium-sulfur(Li–S) batteries.
It can also be used as interface modification material to passivate interface defects in perovskite solar cells.

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Eye Dam. 1 - Skin Corr. 1B

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 1

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Jingru Li et al.
ACS applied materials & interfaces, 12(50), 56017-56026 (2020-12-04)
Uncontrollable dendrite growth and low Coulombic efficiency are the two main obstacles that hinder the application of rechargeable Li metal batteries. Here, an optimized amount of potassium hexafluorophosphate (KPF6, 0.01 M) has been added into the 2 M LiTFSI/ether-based electrolyte
Ruhamah Yunis et al.
Physical chemistry chemical physics : PCCP, 21(23), 12288-12300 (2019-05-30)
The synthesis and characterisation of new solid-state electrolytes is a key step in advancing the development of safer and more reliable electrochemical energy storage technologies. Organic ionic plastic crystals (OIPCs) are an increasingly promising class of material for application in
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Cong-Xiao Cao et al.
Scientific reports, 7(1), 3101-3101 (2017-06-10)
The unusually broad physical and chemical property window of ionic liquids allows for a wide range of applications, which gives rise to the recent spring-up of ionic liquid-based functional materials. Via solvothermal copolymerization of a monomeric ionic liquid and divinylbenzene
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