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200921

Sigma-Aldrich

Silver(II) fluoride

≥98%

Synonym(s):

Silver difluoride

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About This Item

Empirical Formula (Hill Notation):
AgF2
CAS Number:
Molecular Weight:
145.87
EC Number:
MDL number:
UNSPSC Code:
12352302
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

≥98%

form

powder

mp

690 °C (lit.)

density

4.57 g/mL at 25 °C (lit.)

SMILES string

F[Ag]F

InChI

1S/Ag.2FH/h;2*1H/q+2;;/p-2

InChI key

KWVVTSALYXIJSS-UHFFFAOYSA-L

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Application

Silver (II) fluoride may be used for selective fluorination of carbon-hydrogen bond in pyridines and diazines.

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Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Eye Dam. 1 - Ox. Sol. 2 - Skin Corr. 1B

Storage Class

5.1B - Oxidizing hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges, type P3 (EN 143) respirator cartridges


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Slide 1 of 2

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Selective CH fluorination of pyridines and diazines inspired by a classic amination reaction.
Fier PS & Hartwig JF.
Science, 342.6161, 956-960 (2013)

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