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202126

Sigma-Aldrich

Cesium carbonate

99.9% trace metals basis

Synonym(s):

Carbonic acid dicesium

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About This Item

Linear Formula:
Cs2CO3
CAS Number:
Molecular Weight:
325.82
Beilstein/REAXYS Number:
4546405
EC Number:
MDL number:
UNSPSC Code:
12352301
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

99.9% trace metals basis

mp

610 °C (dec.) (lit.)

SMILES string

[Cs+].[Cs+].[O-]C([O-])=O

InChI

1S/CH2O3.2Cs/c2-1(3)4;;/h(H2,2,3,4);;/q;2*+1/p-2

InChI key

FJDQFPXHSGXQBY-UHFFFAOYSA-L

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Application

Catalyst for:
Aerobic oxidation of primary alcohols
1,4-addition reactions

Reagent for:
Synthesis of phosphazene derivatives
Constrictive binding interactions
Intramolecular C-N cross coupling reactions
Dehydrohalogenative polycondensation reactions
Promotes the efficient O-alkylation of alcohols to form mixed alkyl carbonates.

pictograms

CorrosionHealth hazard

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Repr. 2 - STOT RE 2 Oral

Storage Class

13 - Non Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Science advances, 3(10), eaao4204-eaao4204 (2017-11-04)
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Beilstein journal of nanotechnology, 8, 2521-2529 (2017-12-21)
Colloidal perovskite nanocrystals comprised of all inorganic cesium lead halide (CsPbX
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Advanced science (Weinheim, Baden-Wurttemberg, Germany), 4(11), 1700335-1700335 (2017-12-05)
Bright and stable blue emitters with narrow full-width at half-maxima are particularly desirable for applications in television displays and related technologies. Here, this study shows that doping aluminum (Al
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Perovskite nanostructures, both hybrid organo-metal and fully inorganic perovskites, have gained a lot of interest in the past few years for their intriguing optical properties in the visible region. We report on inorganic cesium lead bromide (CsPbBr
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Nanostructured semiconductors emit light from electronic states known as excitons. For organic materials, Hund's rules state that the lowest-energy exciton is a poorly emitting triplet state. For inorganic semiconductors, similar rules predict an analogue of this triplet state known as

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