Skip to Content
MilliporeSigma
All Photos(3)

Documents

209988

Sigma-Aldrich

Zinc

dust, <10 μm, ≥98%

Synonym(s):

Zn

Sign Into View Organizational & Contract Pricing


About This Item

Empirical Formula (Hill Notation):
Zn
CAS Number:
Molecular Weight:
65.39
MDL number:
UNSPSC Code:
12161600
PubChem Substance ID:
NACRES:
NA.22

vapor pressure

1 mmHg ( 487 °C)

Quality Level

assay

≥98%

form

dust

reaction suitability

core: zinc
reagent type: catalyst

resistivity

5.8 μΩ-cm, 20°C

particle size

<10 μm

bp

907 °C (lit.)

mp

420 °C (lit.)

density

7.133 g/mL at 25 °C (lit.)

SMILES string

[Zn]

InChI

1S/Zn

InChI key

HCHKCACWOHOZIP-UHFFFAOYSA-N

General description

Zinc is an inexpensive, readily available versatile reagent in organic reactions and is commonly used as a reducing agent in organic synthesis. Zinc dust is used to reduce carbonyls, carbon-halide bonds, carbon-oxygen bonds, alkynes, and heteroatom bonds such as N-N and N-O bonds. It is also used to prepare various organozinc reagents. Additionally, Zinc has been used in several well-known named reactions, like the Reformatsky reaction, the Knorr pyrrole synthesis, the Serini reaction, and the Simmons-Smith cyclopropanation.

Application

Reducing agent; used for preparation of organozinc reagents, Reformatsky reagents, and the Simmons-Smith reagent (cyclopropanation).

Zinc is also used as a:

  • Reductant in the hydrothermal CO2 reduction to formic acid in batch reactors.
  • Catalyst in the synthesis of propargylamines by one pot, three component coupling of aldehydes, amines and alkynes in acetonitrile.

pictograms

Environment

signalword

Warning

hcodes

Hazard Classifications

Aquatic Acute 1 - Aquatic Chronic 1

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 7

1 of 7

Zinc granular, 30-100&#160;mesh, 99%

Sigma-Aldrich

565148

Zinc

Zinc powder, max. particle size 150 micron, weight 20&#160;g, high purity 99.999%

GF09421095

Zinc

Zinc powder, max. particle size 150 micron, weight 200&#160;g, purity 99.9%

GF03217823

Zinc

Zinc granular for analysis, particle size about 3-8 mm EMSURE&#174; ISO

Supelco

1.08780

Zinc

Zinc preparation 5&#160;g/dL Zn+2 in THF, highly reactive Rieke&#174;metal

Sigma-Aldrich

499552

Zinc preparation

Zinc powder for analysis particle size &#174;

Supelco

1.08789

Zinc

Zinc coarse powder for analysis suitable for filling of reductors, particle size about 0.3- 1.5 mm (14-50 mesh ASTM) EMSURE&#174; Reag. Ph Eur

Supelco

1.08756

Zinc

Nicholas A Isley et al.
Green chemistry : an international journal and green chemistry resource : GC, 2015, 307-307 (2014-12-23)
Alkyl bromides and chlorides can be reduced to the corresponding hydrocarbons utilizing zinc in the presence of an amine additive. The process takes place in water at ambient temperatures, enabled by a commercially available designer surfactant. The reaction medium can
Activated zinc dust
Smith CR
Synlett, 2009(09), 1522-1523 (2009)
Knochel, P.
Chemical Reviews, 93, 217-217 (1993)
Sara Eyal et al.
Journal of nuclear medicine : official publication, Society of Nuclear Medicine, 50(5), 798-806 (2009-05-01)
Studies in rodents indicate that the disruption of P-glycoprotein (P-gp) function increases drug distribution into the developing fetus and organs such as the brain. To simultaneously and serially evaluate the effect of P-gp activity and inhibition on the tissue distribution
A viewpoint about the treatment of Wilson's disease.
Abdul Qayyum Rana et al.
The Canadian journal of neurological sciences. Le journal canadien des sciences neurologiques, 40(4), 612-614 (2013-06-22)

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service