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Sigma-Aldrich

Rhodium on alumina

greener alternative

extent of labeling: 5 wt. % loading, matrix alumina support, powder

Synonym(s):

Rh/Al2O3

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About This Item

MDL number:
MFCD00011201
UNSPSC Code:
12352300
PubChem Substance ID:
24852747
NACRES:
NA.22

form

powder

Quality Level

200

reaction suitability

core: rhodium
reagent type: catalyst

greener alternative product characteristics

Design for Energy Efficiency
Learn more about the Principles of Green Chemistry.

extent of labeling

5 wt. % loading

matrix

alumina support

greener alternative category

Enabling,

SMILES string

[Rh]

InChI

1S/Rh

InChI key

MHOVAHRLVXNVSD-UHFFFAOYSA-N

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for energy efficiency. Find details here.

Application

Rhodium on alumina (Rh/Al2O3) (5 wt. % loading, matrix alumina support, powder) is utilized as a catalyst for the steam reforming of ethanol for use in hydrogen production using molten carbonate fuel cells. Rh/Al2O3 can also be used as a catalyst in the production of hydrogen from sodium borohydride (NaBH4).

Storage Class

13 - Non Combustible Solids

wgk_germany

nwg

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type N95 (US)

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Calorimetric study on oxidation of alumina supported rhodium by dioxygen
Wang, CB, et al.
J. Mol. Catal. A: Chem., 120(1), 179-184 (1997)
Real-time XAFS analysis of Rh/alumina catalyst
Dohmae K, et al.
Surface and Interface Analysis : SIA, 40(13), 1751-1754 (2008)
Performance of Rh/Al2O3 catalyst in the steam reforming of ethanol: H2 production for MCFC
Cavallaro S, et al.
Applied Catalysis A: General, 249(1), 119-128 (2003)
Ethanol steam reforming on Rh/Al2O3 catalysts
Cavallaro S
Energy & Fuels, 14(6), 1195-1199 (2000)
Comparative XPS study of Rh/Al2O3 and Rh/TiO2 as catalysts for NaBH4 hydrolysis
Larichev YV, et al.
International Journal of Hydrogen Energy, 35(13), 6501-6507 (2010)
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