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221007

Sigma-Aldrich

Manganese(II) acetate tetrahydrate

≥99%

Synonym(s):

Manganese Diacetate Tetrahydrate, Manganous acetate

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About This Item

Linear Formula:
(CH3COO)2Mn · 4H2O
CAS Number:
Molecular Weight:
245.09
Beilstein/REAXYS Number:
3730728
EC Number:
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.23

Quality Level

assay

≥99%

form

crystals

reaction suitability

core: manganese

mp

>300 °C (lit.)

density

1.589 g/mL at 25 °C (lit.)

SMILES string

[H]O[H].[H]O[H].[H]O[H].[H]O[H].CC(=O)O[Mn]OC(C)=O

InChI

1S/2C2H4O2.Mn.4H2O/c2*1-2(3)4;;;;;/h2*1H3,(H,3,4);;4*1H2/q;;+2;;;;/p-2

InChI key

CESXSDZNZGSWSP-UHFFFAOYSA-L

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Application

Manganese(ll) acetate tetrahydrate can be used as:
  • A starting material in the synthesis of manganese carboxylates, which are used to prepare manganese oxide thin films by chemical vapor deposition(CVD).
  • A precursor in the synthesis of manganese-TiO2 composites by chemical vapor condensation(CVC).These composites are used in the oxidation of NO at low temperatures.    
  • A precursor in preparation of NCM( LiNi1/3Co1/3Mn1/3O2) powder applicable as cathode material in lithium-ion batteries.

pictograms

Health hazard

signalword

Warning

Hazard Classifications

Aquatic Chronic 3 - STOT RE 2 Inhalation

target_organs

Brain

Storage Class

11 - Combustible Solids

wgk_germany

WGK 2

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves


Certificates of Analysis (COA)

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Carbon coating nanostructured-LiNi1/3Co1/3Mn1/3O2 cathode material synthesized by chemical vapor deposition method for high performance lithium-ion batteries
Qian Hou, et al.
Journal of alloys and compounds, 747, 796-802 (2018)
Cobalt and manganese carboxylates for metal oxide thin film deposition by applying the atmospheric pressure combustion chemical vapour deposition process
Kretzschmar,et al.
Royal Society of Chemistry Advances, 8(28), 15632-15640 (2018)
Renfa Liu et al.
Theranostics, 5(10), 1144-1153 (2015-08-19)
The integration of diagnostic and therapeutic functionalities into one nanoplatform shows great promise in cancer therapy. In this research, manganese (II) chelate functionalized copper sulfide nanoparticles were successfully prepared using a facile hydrothermal method. The obtained ultrasmall nanoparticles exhibit excellent
Kyu-Nam Jung et al.
Scientific reports, 5, 7665-7665 (2015-01-08)
Rechargeable metal-air batteries are considered a promising energy storage solution owing to their high theoretical energy density. The major obstacles to realising this technology include the slow kinetics of oxygen reduction and evolution on the cathode (air electrode) upon battery
Rusi et al.
PloS one, 10(7), e0129780-e0129780 (2015-07-15)
The composite metal oxide electrode films were fabricated using ex situ electrodeposition method with further heating treatment at 300°C. The obtained composite metal oxide film had a spherical structure with mass loading from 0.13 to 0.21 mg cm(-2). The structure

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