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Aluminum-nickel catalyst

Al-Ni 50:50 wt. %

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About This Item

Empirical Formula (Hill Notation):
AlNi
CAS Number:
Molecular Weight:
85.67
MDL number:
UNSPSC Code:
12352300
PubChem Substance ID:
NACRES:
NA.22

composition

Al-Ni, 50:50 wt. %

Quality Level

reaction suitability

core: nickel
reagent type: catalyst

manufacturer/tradename

W.R. Grace and Co. Raney®

density

3.46 g/mL at 25 °C (lit.)

SMILES string

[Al].[Ni]

InChI

1S/Al.Ni

InChI key

NPXOKRUENSOPAO-UHFFFAOYSA-N

Application

Catalyst for:
  • Reduction reactions
  • Reductive dehalogenation and ring saturation reactions

Used for:
  • Preparation of aluminum oxy-hydrate supported NiAl skeleton catalyst for hydrogenation reactions
Raney-type alloy for the preparation of Raney® Nickel catalyst. ,

Legal Information

Raney is a registered trademark of W.R. Grace & Co.-Conn.

signalword

Danger

Hazard Classifications

Carc. 2 - Flam. Sol. 1 - Skin Sens. 1 - Water-react 2

Storage Class

4.3 - Hazardous materials, which set free flammable gases upon contact with water

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges


Certificates of Analysis (COA)

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Jaeyong Park et al.
ChemSusChem, 12(8), 1743-1762 (2019-02-01)
Highly dispersed, core-shell Ni@Al2 O3 on activated carbon (AC) catalysts were prepared to develop an effective, external-hydrogen-free fractionation process for various types of lignocellulosic biomass. In a mixture of formic acid, ethanol, and water at 190 °C, the conversion of oak

Articles

Nickel transition metal and its complexes can be used as a catalyst in many synthetic transformations, like oxidative addition, C-H activation, reductive elimination, oxidative cyclization, oligomerization, and in cross-coupling reactions.

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