247383
Boron tribromide dimethyl sulfide complex solution
1.0 M in methylene chloride
Synonym(s):
Dimethyl sulfide-tribromoborane, Tribromoborane-methyl sulfide
About This Item
Recommended Products
form
liquid
Quality Level
concentration
1.0 M in methylene chloride
density
1.456 g/mL at 25 °C
SMILES string
C[S+](C)[B-](Br)(Br)Br
InChI
1S/C2H6BBr3S/c1-7(2)3(4,5)6/h1-2H3
InChI key
NCVLHAUANAMSTL-UHFFFAOYSA-N
Related Categories
Application
- To prepare demethylated products from aryl methyl ethers by deprotection of methyl groups.
- To hydrolyze 1,3-methylenedioxole ring compounds to 1,2-dihydroxy compounds.
- To prepare benzyl S,S′-diphenyl acetal by reacting with phenylacetic acid and thexylphenylthioborane.
- To synthesize Baylis−Hillman adducts and α-halomethyl enones by the reaction between aldehydes and 3-buten-2-one.
- Precursor of HIV protease inhibitor KNI 764 using cation-exchange resin mediated Mannich reaction
Reagent for:
- Baylis-Hillman reactions
signalword
Danger
hcodes
Hazard Classifications
Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
target_organs
Central nervous system
supp_hazards
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificates of Analysis (COA)
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