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Sigma-Aldrich

1-(tert-Butyldimethylsilyl)imidazole

≥95%

Synonym(s):

TBDMSIM

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About This Item

Empirical Formula (Hill Notation):
C9H18N2Si
CAS Number:
54925-64-3
Molecular Weight:
182.34
Beilstein/REAXYS Number:
606695
EC Number:
259-398-1
MDL number:
MFCD00011682
UNSPSC Code:
12352005
PubChem Substance ID:
24855044
NACRES:
NA.22

assay

≥95%

form

liquid

refractive index

n20/D 1.481 (lit.)

bp

53 °C/0.2 mmHg (lit.)

density

0.939 g/mL at 25 °C (lit.)

SMILES string

CC(C)(C)[Si](C)(C)n1ccnc1

InChI

1S/C9H18N2Si/c1-9(2,3)12(4,5)11-7-6-10-8-11/h6-8H,1-5H3

InChI key

VUENSYJCBOSTCS-UHFFFAOYSA-N

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General description

1-(tert-Butyldimethylsilyl)imidazole is a reactive silylating agent.

Packaging

Bottomless glass bottle. Contents are inside inserted fused cone.

related product

Product No.
Description
Pricing

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

210.2 °F

flash_point_c

99 °C

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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tert-Butyldimethylsilyl chloride reagent grade, 97%

Sigma-Aldrich

190500

tert-Butyldimethylsilyl chloride

P Bydal et al.
Steroids, 61(6), 349-353 (1996-06-01)
Five dehydrated compounds obtained from a tert-butyldimethylsilylchloride/imidazole or an aqueous hydrochloric acid treatment of 17 alpha-butyl-3-O-methyl estradiol in refluxing solvent were purified and characterized. Three compounds were obtained from a direct vicinal proton elimination, the two others from a vicinal
D C Landrum et al.
Journal of chromatography, 483, 21-32 (1989-12-08)
The use of gas-liquid chromatography and mass spectrometry with derivatizing agents that give stable derivatives and consistent fragmentation patterns allows for accurate identification of a variety of compounds. In this study either N-methyl-N-tert.-butyldimethylsilyltrifluoroacetamide or N-tert.-butyldimethylsilylimidazole were employed to derivatize a

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