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Sigma-Aldrich

1-Naphthoyl chloride

97%

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About This Item

Linear Formula:
C10H7COCl
CAS Number:
879-18-5
Molecular Weight:
190.63
Beilstein/REAXYS Number:
775785
EC Number:
212-903-9
MDL number:
MFCD00004002
UNSPSC Code:
12352100
PubChem Substance ID:
24855045
NACRES:
NA.22

Quality Level

100

assay

97%

form

liquid

refractive index

n20/D 1.652 (lit.)

bp

190 °C/35 mmHg (lit.)

mp

16-19 °C (lit.)

density

1.265 g/mL at 25 °C (lit.)

SMILES string

ClC(=O)c1cccc2ccccc12

InChI

1S/C11H7ClO/c12-11(13)10-7-3-5-8-4-1-2-6-9(8)10/h1-7H

InChI key

NSNPSJGHTQIXDO-UHFFFAOYSA-N

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Application

1-Naphthoyl chloride has been used:
  • as derivatization reagent in analysis of short-chained dodecyl alcohol ethoxylates and dodecyl alcohol by solid-phase extraction combined with dispersive liquid-liquid microextraction method
  • as fluorescent labeling reagent in determination of T-2 and HT-2 toxins by HPLC with fluorescence detection
  • in Arndt-Eistert synthesis in the presence of trimethylsilyldiazomethane
  • in preparation of 2-ethyl-1-pentyl-3-(1-naphthoyl)indole

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

230.0 °F - closed cup

flash_point_c

> 110 °C - closed cup

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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2-Naphthoic acid 98%

Sigma-Aldrich

180246

2-Naphthoic acid

2-(Chloromethyl)naphthalene ≥97.0%

Sigma-Aldrich

726419

2-(Chloromethyl)naphthalene

New methods and reagents in organic synthesis. 8. Trimethylsilyldiazomethane. A new, stable, and safe reagent for the classical arndt-eistert synthesis.
Aoyama T and Shioiri T.
Tetrahedron Letters, 21(46), 4461-4462 (1980)
Vincenzo Lippolis et al.
Talanta, 74(5), 1476-1483 (2008-03-29)
T-2 and HT-2 toxins are Fusarium mycotoxins that can occur in cereals and cereal-based products. Three fluorescent labeling reagents, i.e. 1-naphthoyl chloride (1-NC), 2-naphthoyl chloride (2-NC) and pyrene-1-carbonyl cyanide (PCC), were used for the determination of T-2 and HT-2 toxins
John W Huffman et al.
Bioorganic & medicinal chemistry, 11(4), 539-549 (2003-01-23)
A series of 1-pentyl-1H-indol-3-yl-(1-naphthyl)methanes (9-11) and 2-methyl-1-pentyl-1H-indol-3-yl-(1-naphthyl)methanes (12-14) have been synthesized to investigate the hypothesis that cannabimimetic 3-(1-naphthoyl)indoles interact with the CB(1) receptor by hydrogen bonding to the carbonyl group. Indoles 9-11 have significant (K(i)=17-23nM) receptor affinity, somewhat less than
Agnieszka Zgoła-Grześkowiak et al.
Journal of chromatography. A, 1251, 40-47 (2012-07-10)
A new method was developed for preconcentration, derivatisation and analysis of short-chained dodecyl alcohol ethoxylates and dodecyl alcohol. Solid-phase extraction combined with dispersive liquid-liquid microextraction was used for preconcentration of target compounds. Several parameters were optimised including different solid phase

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