Skip to Content
MilliporeSigma
All Photos(1)

Documents

252387

Sigma-Aldrich

Pentafluoropropionic anhydride

99%

Synonym(s):

PFPA, Perfluoropropionic anhydride

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
(CF3CF2CO)2O
CAS Number:
356-42-3
Molecular Weight:
310.05
Beilstein/REAXYS Number:
1806446
EC Number:
206-604-2
MDL number:
MFCD00000429
UNSPSC Code:
12352100
PubChem Substance ID:
24855205
NACRES:
NA.22

Quality Level

100

assay

99%

form

liquid

bp

69-70 °C/735 mmHg (lit.)

density

1.571 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C(F)(F)C(=O)OC(=O)C(F)(F)C(F)(F)F

InChI

1S/C6F10O3/c7-3(8,5(11,12)13)1(17)19-2(18)4(9,10)6(14,15)16

InChI key

XETRHNFRKCNWAJ-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Pentafluoropropionic anhydride was used:
  • in preparation of halogenated derivatives of phenolic acids, required for determination of some biologically important acids in cerebrospinal fluid
  • as derivatization reagent in detection of 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain by GC-multiple ion detection
  • in simultaneous determination of the major metabolites of dopamine in rat striatum by gas-liquid chromatography

pictograms

Corrosion
GHS05

signalword

Danger

hcodes

H314

Hazard Classifications

Skin Corr. 1B

supp_hazards

EUH014

Storage Class

8A - Combustible, corrosive hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 6

1 of 6

Trichloroacetic anhydride technical grade, 95%

Sigma-Aldrich

367710

Trichloroacetic anhydride

Trifluoroacetic anhydride for GC derivatization, LiChropur™, ≥99.0% (GC)

Supelco

91719

Trifluoroacetic anhydride

N,O-Bis(trimethylsilyl)trifluoroacetamide ≥99%

Sigma-Aldrich

155195

N,O-Bis(trimethylsilyl)trifluoroacetamide

Perfluoropentanoic acid 97%

Sigma-Aldrich

396575

Perfluoropentanoic acid

Supelco

Supelco

50992

N-Methyl-N-trimethylsilyltrifluoroacetamide activated I

Pentafluorophenyl acrylate contains <200 ppm monomethyl ether hydroquinone as inhibitor, 98%

Sigma-Aldrich

753092

Pentafluorophenyl acrylate

M Kohno et al.
Biochemical and biophysical research communications, 140(1), 448-454 (1986-10-15)
This is the first report to identify 1,2,3,4-tetrahydroisoquinoline and 1-methyl-1,2,3,4-tetrahydroisoquinoline as endogenous amines from non-treated rat brain. The detection was performed by coupled gas chromatography - multiple ion detection, using heptafluorobutyric anhydride and pentafluoropropionic anhydride as derivatizing reagents. These amines
Derivatization and gas chromatographic determination of some biologically important acids in cerebrospinal fluid.
E Watson et al.
Analytical biochemistry, 59(2), 441-451 (1974-06-01)
Simultaneous determination of 3,4-dihydroxyphenylacetic acid and homovanillic acid in milligram amounts of rat striatal tissue by gas-liquid chromatography.
E Watson et al.
Life sciences, 15(12), 2167-2178 (1974-12-15)
Y S Oh-Shin et al.
Journal of chromatography. A, 769(2), 285-291 (1997-05-09)
A rapid and simple gas chromatographic method for the simultaneous determination of malathion, parathion, fenitrothion, diazinon and carbaryl in drinking water is presented. A fused-silica SE-54 column was used for the separation of the insecticides and was split into two
I Jakasa et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 811(2), 177-182 (2004-11-04)
We developed a sensitive method for determination of polyethylene glycols (PEGs) of different molecular weight (MW) in the human stratum corneum (SC) obtained by tape stripping. The analysis is based on derivatization with pentafluoropropionic anhydride (PFPA) and gas chromatography-electron capture
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service