Skip to Content
MilliporeSigma
All Photos(1)

Documents

254517

Sigma-Aldrich

Trimethyl orthovalerate

97%

Synonym(s):

1,1,1-Trimethoxypentane

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
CH3CH2CH2CH2C(OCH3)3
CAS Number:
13820-09-2
Molecular Weight:
162.23
Beilstein/REAXYS Number:
1739200
EC Number:
237-496-5
MDL number:
MFCD00008481
UNSPSC Code:
12352100
PubChem Substance ID:
24855389
NACRES:
NA.22

Quality Level

200

assay

97%

refractive index

n20/D 1.410 (lit.)

bp

164-166 °C (lit.)

density

0.941 g/mL at 25 °C (lit.)

SMILES string

CCCCC(OC)(OC)OC

InChI

1S/C8H18O3/c1-5-6-7-8(9-2,10-3)11-4/h5-7H2,1-4H3

InChI key

XUXVVQKJULMMKX-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Kinetics of unimolecular gas-phase elimination of trimethyl orthovalerate has been investigated.

Application

Trimethyl orthovalerate has been used in the preparation of:
  • various 9-O-acyl derivatives of N-acetyl- and N-glycoloyl-neuraminic acid
  • 2-methyl, 2-ethyl, 2-propyl and 2-butyl-3-benzimidazolyl-4(3H)-quinazolinones

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2

wgk_germany

WGK 3

flash_point_f

107.6 °F

flash_point_c

42 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Edgar Marquez et al.
The journal of physical chemistry. A, 114(12), 4203-4209 (2010-03-10)
The rates of gas-phase elimination of trimethyl orthovalerate and trimethyl orthochloroacetate have been determined in a static system, and the reaction Pyrex vessels have been deactivated with the product of decomposition of allyl bromide. The reactions are unimolecular and follow
A facile synthesis of new 3-(2-benzimidazolyl)-2-alkyl-4-(3H)-quinazolinones under microwave irradiation.
Hazarkhani H and Karimi B.
Tetrahedron, 59(26), 4757-4760 (2003)
H Ogura et al.
Carbohydrate research, 167, 77-86 (1987-09-15)
Various 9-O-acyl derivatives of N-acetyl- and N-glycoloyl-neuraminic acid, and O-(5-acetamido-3,5-dideoxy-D-glycero-alpha- and beta-D-galacto-2-nonulopyranosylonic acid)-(2----6)-O-beta-D-galactopyranosyl-(1----4)-D-glucopyranose were regioselectively synthesized by use of ortho esters. In addition, 5-acetamido-4-O-acetyl-D-glycero-D-galacto-2-nonulopyranosonic acid was prepared starting from the benzyl and methyl esters of N-acetylneuraminic acid.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service