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276766

Sigma-Aldrich

1-Acetonaphthone

97%

Synonym(s):

1-Acetylnaphthalene, Methyl 1-naphthyl ketone

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About This Item

Linear Formula:
C10H7COCH3
CAS Number:
941-98-0
Molecular Weight:
170.21
Beilstein/REAXYS Number:
1100618
EC Number:
213-384-1
MDL number:
MFCD00004013
UNSPSC Code:
12352100
PubChem Substance ID:
24856716
NACRES:
NA.22

Quality Level

200

assay

97%

refractive index

n20/D 1.628 (lit.)

bp

302 °C (lit.)

mp

10.5 °C (lit.)

density

1.12 g/mL at 25 °C (lit.)

SMILES string

CC(=O)c1cccc2ccccc12

InChI

1S/C12H10O/c1-9(13)11-8-4-6-10-5-2-3-7-12(10)11/h2-8H,1H3

InChI key

QQLIGMASAVJVON-UHFFFAOYSA-N

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General description

Stereoselective reduction of 1-acetonapthone in aqueous media by whole cells of Geotrichum candidum has been investigated in various organic co-solvents. Magnetic field effects on the photoinduced electron-transfer reaction between 1-acetonaphthone and diphenylamine in micellar solution have been studied by laser flash photolysis.

pictograms

Exclamation mark
GHS07

signalword

Warning

hcodes

H302,H412

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3

wgk_germany

WGK 2

flash_point_f

>212.0 °F

flash_point_c

> 100 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

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Magnetic field effects on the photoinduced electron-transfer reaction of 1-acetonaphthone and diphenylamine in micellar solution.
Tanimoto Y, et al.
Chemical Physics Letters, 129(4), 414-418 (1986)
Mani Shankar Bhattacharyya et al.
New biotechnology, 29(3), 359-364 (2011-08-13)
Sixteen organic co-solvents were screened for stereoselective reduction of 1-acetonapthone in aqueous media by whole cells of Geotrichum candidum. Benzyl alcohol was found to be a good co-solvent as it afforded a high coversion and reduced deactivation of the cells.
Babu Balaji et al.
European journal of medicinal chemistry, 92, 332-341 (2015-01-13)
Oxovanadium(IV) complexes [VO(Fc-tpy)(acac)](ClO4) (1), [VO(Fc-tpy)(nap-acac)](ClO4) (2), [VO(Fc-tpy)(py-acac)](ClO4) (3) and [VO(Ph-tpy)(py-acac)](ClO4) (4) of 4'-ferrocenyl-2,2':6',2"-terpyridine (Fc-tpy) and 4'-phenyl-2,2':6',2"-terpyridine (Ph-tpy) having monoanionic acetylacetonate (acac), naphthylacetylacetonate (nap-acac) or pyrenylacetylacetonate (py-acac) ligand were prepared, characterized and their photocytotoxicity in visible light studied. The ferrocenyl complexes

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