Skip to Content
MilliporeSigma
All Photos(2)

Documents

281506

Sigma-Aldrich

Methyl 4-methoxyacetoacetate

97%

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
CH3OCH2COCH2COOCH3
CAS Number:
41051-15-4
Molecular Weight:
146.14
Beilstein/REAXYS Number:
1761215
EC Number:
255-188-9
MDL number:
MFCD00010183
UNSPSC Code:
12352100
PubChem Substance ID:
24856977
NACRES:
NA.22

assay

97%

form

liquid

refractive index

n20/D 1.431 (lit.)

bp

89 °C/8.5 mmHg (lit.)

density

1.129 g/mL at 25 °C (lit.)

SMILES string

COCC(=O)CC(=O)OC

InChI

1S/C6H10O4/c1-9-4-5(7)3-6(8)10-2/h3-4H2,1-2H3

InChI key

QGBPKJFJAVDUNC-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

Application

Methyl 4-methoxyacetoacetate has been used in generation of a small focused library of diversely functionalized dihydropyrimidine derivatives via one-pot three-component Biginelli cyclocondensation of β-ketoesters, aldehydes and (thio)ureas.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

10 - Combustible liquids

wgk_germany

WGK 3

flash_point_f

188.6 °F - closed cup

flash_point_c

87 °C - closed cup

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Doris Dallinger et al.
Nature protocols, 2(7), 1713-1721 (2007-07-21)
Here we report the generation of a small focused library of 12 diversely functionalized dihydropyrimidine (DHPM) derivatives via one-pot three-component Biginelli cyclocondensation of beta-ketoesters, aldehydes and (thio)ureas. By applying controlled microwave heating under sealed vessel conditions using a fully automated

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service