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282316

Sigma-Aldrich

Perfluoro-1,3-dimethylcyclohexane

technical grade, 80%

Synonym(s):

Decafluoro-1,3-bis(trifluoromethyl)cyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane, Hexadecafluoro-1,3-dimethylcyclohexane (cis+trans)

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About This Item

Linear Formula:
C6F10(CF3)2
CAS Number:
335-27-3
Molecular Weight:
400.06
Beilstein/REAXYS Number:
2064147
EC Number:
206-386-9
MDL number:
MFCD00001469
UNSPSC Code:
12352100
PubChem Substance ID:
24857038
NACRES:
NA.22

grade

technical grade

Quality Level

100

vapor density

14 (vs air)

assay

80%

form

liquid

refractive index

n20/D 1.3 (lit.)

bp

101-102 °C (lit.)

mp

−55 °C (lit.)

density

1.828 g/mL at 25 °C (lit.)

SMILES string

FC(F)(F)C1(F)C(F)(F)C(F)(F)C(F)(F)C(F)(C(F)(F)F)C1(F)F

InChI

1S/C8F16/c9-1(7(19,20)21)3(11,12)2(10,8(22,23)24)5(15,16)6(17,18)4(1,13)14

InChI key

LOQGSOTUHASIHI-UHFFFAOYSA-N

Related Categories

General description

Quenching of the second excited singlet state of xanthione in inert, nonpolar perfluoro-1,3-dimethylcyclohexane has been studied using picosecond time-resolved fluorescence decay methods.

Application

Perfluoro-1,3-dimethylcyclohexane has been used in:
  • the preparation of amorphous fluorocarbon films by plasma polymerization
  • hydroformylation of linear terminal alkenes using rhodium based catalysts under fluorous biphasic conditions in the presence and absence of toluene

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Meagan M Gadzuk-Shea et al.
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Understanding the structures of proteins in the gas phase is essential for using gas-phase measurements to infer the properties of proteins in solution. Using serum albumin as a model, this study aims to expand our understanding of this relationship for
Electrical and optical properties of amorphous fluorocarbon films prepared by plasma polymerization of perfluoro-1, 3-dimethylcyclohexane.
Weber A, et al.
Journal of Vacuum Science & Technology. A, Vacuum, Surfaces, And Films, 16(4), 2120-2124 (1998)
Hydroformylation in perfluorinated solvents; improved selectivity, catalyst retention and product separation.
<BIG>Foster DF, et al. </BIG>
Tetrahedron, 58(20), 3901-3910 (2002)
Transient effects in the fluorescence quenching of xanthione in perfluoro-1, 3-dimethylcyclohexane.
Maciejewski A, et al.
International Journal of Radiation Applications and Instrumentation, Part B: Nuclear Medicine and Biology, 39(1), 155-158 (1992)
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Journal of chromatography. A, 1364, 128-139 (2014-09-10)
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