Skip to Content
MilliporeSigma
All Photos(1)

Documents

283479

Sigma-Aldrich

Diethyl diallylmalonate

98%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
(H2C=CHCH2)2C(CO2C2H5)2
CAS Number:
3195-24-2
Molecular Weight:
240.30
EC Number:
221-696-4
MDL number:
MFCD00009126
UNSPSC Code:
12352100
PubChem Substance ID:
24857107
NACRES:
NA.22

Quality Level

100

assay

98%

form

liquid

refractive index

n20/D 1.446 (lit.)

bp

128-130 °C/12 mmHg (lit.)

density

0.994 g/mL at 25 °C (lit.)

SMILES string

CCOC(=O)C(CC=C)(CC=C)C(=O)OCC

InChI

1S/C13H20O4/c1-5-9-13(10-6-2,11(14)16-7-3)12(15)17-8-4/h5-6H,1-2,7-10H2,3-4H3

InChI key

LYUUVYQGUMRKOV-UHFFFAOYSA-N

Related Categories

General description

Low catalyst loading in ring-closing metathesis reaction of diethyl diallylmalonate has been reported. Cationic nickel (with monodentate phosphoramidites and Wilke′s azaphospholene as ligands) catalyzed cycloisomerisation of diethyl diallylmalonate has been reported.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

235.4 °F - closed cup

flash_point_c

113 °C - closed cup

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 7

1 of 7

USP

USP

1708729

Valproic Acid Related Compound A

Allyl ether 98%

Sigma-Aldrich

259470

Allyl ether

2,6-Diisopropylphenylimido-neophylidene[(S)-(−)-BIPHEN]molybdenum(VI) ringclosing metathesis catalyst, ≥95.0% (C)

Sigma-Aldrich

73022

2,6-Diisopropylphenylimido-neophylidene[(S)-(−)-BIPHEN]molybdenum(VI)

Grubbs Catalyst® M101 Umicore

Sigma-Aldrich

774901

Grubbs Catalyst® M101

Tricyclohexylphosphine

Sigma-Aldrich

261971

Tricyclohexylphosphine

Hoveyda-Grubbs Catalyst® M720 Umicore, 97%

Sigma-Aldrich

569755

Hoveyda-Grubbs Catalyst® M720

3-Chloro-3-methyl-1-butyne 97%

Sigma-Aldrich

301345

3-Chloro-3-methyl-1-butyne

Renat Kadyrov
Chemistry (Weinheim an der Bergstrasse, Germany), 19(3), 1002-1012 (2012-11-28)
An efficient procedure is described for ring-closing metathesis reactions. A conversion of 95% for diethyl diallylmalonate in dilute solution could be achieved within a few minutes, reaching TOF = 4173 min(-1), with very low loading of commercially available Ru catalysts that
Christian Böing et al.
Chemical communications (Cambridge, England), (11)(11), 1456-1458 (2005-03-10)
Cationic nickel catalysts with monodentate phosphoramidites and Wilke's azaphospholene as ligands are highly regio- and enantioselective catalysts for the cycloisomerisation of diethyl diallylmalonate.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service