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About This Item
Linear Formula:
C6H5CON(OCH3)CH3
CAS Number:
Molecular Weight:
165.19
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
Recommended Products
Quality Level
assay
98%
form
liquid
refractive index
n20/D 1.533 (lit.)
bp
70 °C/0.1 mmHg (lit.)
density
1.085 g/mL at 25 °C (lit.)
SMILES string
CON(C)C(=O)c1ccccc1
InChI
1S/C9H11NO2/c1-10(12-2)9(11)8-6-4-3-5-7-8/h3-7H,1-2H3
InChI key
UKERDACREYXSIV-UHFFFAOYSA-N
Related Categories
General description
N-Methoxy-N-methylbenzamide is an N,N-disubstituted benzamide. also referred as Weinreb amide., Hydrogen bonding interactions between thioacetamide and N-methoxy-N-methylbenzamide has been investigated using near-infrared absorption spectroscopy. Preparation of N-methoxy-N-methylbenzamide has been reported.
Application
N-Methoxy-N-methylbenzamide may be used in the preparation of β-trifluoromethyl enaminones.
wgk_germany
WGK 3
flash_point_f
closed cup
flash_point_c
closed cup
Certificates of Analysis (COA)
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An efficient conversion of carboxylic acids into Weinreb amides.
Katritzky AR, et al.
ARKIVOC (Gainesville, FL, United States), 11, 39-44 (2002)
Near-infrared spectroscopic studies of the hydrogen bonding between thioacetamide and< i> N</i>,< i> N</i>-disubstituted benzamide derivatives in CCl< sub> 4</sub>.
Choi YS, et al.
Spectrochimica Acta. Part A, Molecular and Biomolecular Spectroscopy, 52(13), 1779-1783 (1996)
A novel approach to ?-trifluoromethyl enaminones.
Jeong IH, et al.
Tetrahedron Letters, 43(40), 7171-7174 (2002)
Kazuhito Hioki et al.
Chemical & pharmaceutical bulletin, 52(4), 470-472 (2004-04-02)
Weinreb amides were successfully prepared from the corresponding carboxylic acids using 4-(4,6-dimethoxy-1,3,5-triazin-2-yl)-4-methylmorpholinium chloride (DMT-MM) in the solvents, methanol, isopropyl alcohol, and acetonitrile, which can solubilize DMT-MM. A variety of carboxylic acids were converted to the corresponding Weinreb amides in excellent
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