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407518

Sigma-Aldrich

Julolidine hydrobromide

97%

Synonym(s):

2,3,6,7-Tetrahydro-1H,5H-benzo[ij]quinolizine hydrobromide

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About This Item

Empirical Formula (Hill Notation):
C12H15N · HBr
CAS Number:
83646-41-7
Molecular Weight:
254.17
MDL number:
MFCD00198009
UNSPSC Code:
12352100
PubChem Substance ID:
24865457
NACRES:
NA.22

Quality Level

100

assay

97%

form

powder

mp

239-242 °C (lit.)

SMILES string

Br.C1CN2CCCc3cccc(C1)c23

InChI

1S/C12H15N.BrH/c1-4-10-6-2-8-13-9-3-7-11(5-1)12(10)13;/h1,4-5H,2-3,6-9H2;1H

InChI key

KHWBRFVBPGPEOJ-UHFFFAOYSA-N

Related Categories

General description

Julolidines are effective auxofluors that are employed in laser dyes and biochemical stains. They are known to be one of the strongest electron-releasing groups due to electronic and steric factors.

Application

Julolidine hydrobromide may be used in the synthesis of [4-(2,3,6,7-tetrahydro-1H,5H-pyrido[3,2,1-ij]quinolin-9-ylazo)-phenyl]-methanol azodye.

pictograms

Skull and crossbonesCorrosion
GHS06,GHS05

signalword

Danger

Hazard Classifications

Acute Tox. 3 Oral - Eye Dam. 1 - Skin Corr. 1B

supp_hazards

EUH014

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Synthesis, optical characterization and crystal and molecular X-ray structure of a phenylazojulolidine derivative.
Barbero N, et al.
Dyes and Pigments, 92(3), 1177-1183 (2012)
Synthesis of julolidine derivatives.
Kauffman JM, et al.
Organic preparations and procedures international, 33(6), 603-613 (2001)

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