Skip to Content
MilliporeSigma
All Photos(3)

Documents

434876

Sigma-Aldrich

Chloroform-d

99.8 atom % D, contains 0.1 % (v/v) TMS

Synonym(s):

Deuterochloroform

Sign Into View Organizational & Contract Pricing
All Photos(3)

About This Item

Linear Formula:
CDCl3
CAS Number:
865-49-6
Molecular Weight:
120.38
Beilstein/REAXYS Number:
1697633
EC Number:
212-742-4
MDL number:
MFCD00000827
UNSPSC Code:
12142201
PubChem Substance ID:
24867214
NACRES:
NA.21

isotopic purity

99.8 atom % D

Quality Level

200

assay

≥99.00%

form

liquid

contains

0.1 % (v/v) TMS

technique(s)

NMR: suitable

impurities

≤0.0100% water
water

refractive index

n20/D 1.444 (lit.)

bp

60.9 °C (lit.)

mp

−64 °C (lit.)

density

1.500 g/mL at 25 °C (lit.)

mass shift

M+1

SMILES string

[2H]C(Cl)(Cl)Cl

InChI

1S/CHCl3/c2-1(3)4/h1H/i1D

InChI key

HEDRZPFGACZZDS-MICDWDOJSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Chloroform-d (deuterochloroform, CDCl3) is a deuterated NMR solvent containing 0.1 % (v/v) TMS (tetramethylsilane). It is useful in NMR-based research and analyses. It may be synthesized by reacting trichloroacetophenone and sodium deuteroxide. The influence of the number of pulses on its multiphoton decomposition (MPD) has been studied. Infrared spectral studies of C-D stretching and bending motions of CDCl3 in different solvents have been investigated. The effect of chloroform-d on the interaction of water with activated carbons has been analyzed. The dependence of molecular reorientation of deuterated chloroform on pressure and temperature has been studied by Raman spectroscopy.

Application

Chloroform-d may be used in the synthesis of dichlorofluoromethane-d.

Recommended products

Check out ChemisTwin®, our brand new online portal for identity confirmation and quantification of NMR spectra. Learn more or reach out to us for a free trial.

pictograms

Skull and crossbonesHealth hazard
GHS06,GHS08

signalword

Danger

Hazard Classifications

Acute Tox. 3 Inhalation - Acute Tox. 4 Oral - Carc. 2 - Eye Irrit. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Oral - STOT SE 3

target_organs

Central nervous system

Storage Class

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 7

1 of 7

Chloroform-d ≥99.8 atom % D, contains 0.5 wt. % silver foil as stabilizer

Sigma-Aldrich

416754

Chloroform-d

Methanol-d4 ≥99.8 atom % D, contains 0.1 % (v/v) TMS

Sigma-Aldrich

439029

Methanol-d4

Acetone-d6 99.9 atom % D, contains 0.03 % (v/v) TMS

Sigma-Aldrich

434531

Acetone-d6

Dimethyl sulfoxide-d6 99.9 atom % D, contains 1 % (v/v) TMS

Sigma-Aldrich

185965

Dimethyl sulfoxide-d6

Methanol-d4 ≥99.8 atom % D

Sigma-Aldrich

151947

Methanol-d4

Corning® 15 mL centrifuge tubes conical bottom natural PET, sterile, bag of 50 (bulk packed), cap (plug seal), case of 500

CLS430053

Corning® 15 mL centrifuge tubes

Methanol-d4 ≥99.8 atom % D, contains 0.05 % (v/v) TMS

Sigma-Aldrich

611646

Methanol-d4

Isotope Effect on Dissociation Probabilities in the Mass Spectra of Chloroform and Chloroform-d.
Dibeler VH and Bernstein RB.
J. Chem. Phys., 19(4), 404-406 (1951)
The effect of collisions in the multiphoton decomposition of chloroform-d.
McRae GA, et al.
J. Chem. Phys. , 92(10), 5997-6003 (1990)
Influence of organics on the structure of water adsorbed on activated carbons.
Turov VV, et al.
Journal of Colloid and Interface Science, 253(1), 23-34 (2002)
Raman study of molecular reorientation in liquid chloroform and chloroform-d under high pressure.
Schroeder J, et al.
J. Chem. Phys. , 69(12), 5479-5488 (1978)
Dichlorofluoromethane-d: a versatile solvent for VT-NMR experiments.
Siegel JS and Anet FAL.
The Journal of Organic Chemistry, 53(11), 2629-2630 (1988)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service