Skip to Content
MilliporeSigma
All Photos(2)

Documents

481718

Sigma-Aldrich

Iron(0) pentacarbonyl

greener alternative

>99.99% trace metals basis

Synonym(s):

Iron(0) carbonyl, Pentacarbonyliron(0)

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
Fe(CO)5
CAS Number:
13463-40-6
Molecular Weight:
195.90
EC Number:
236-670-8
MDL number:
MFCD00011001
UNSPSC Code:
12352300
PubChem Substance ID:
24871777
NACRES:
NA.23

vapor density

6.74 (vs air)

Quality Level

100

vapor pressure

35 mmHg ( 25 °C)
40 mmHg ( 30.3 °C)

assay

>99.99% trace metals basis

form

liquid

autoignition temp.

122 °F

reaction suitability

core: iron
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

refractive index

n20/D 1.5196 (lit.)

bp

103 °C (lit.)

mp

−20 °C (lit.)

density

1.49 g/mL at 25 °C (lit.)

greener alternative category

, Aligned

storage temp.

2-8°C

SMILES string

[Fe].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+].[C-]#[O+]

InChI

1S/5CO.Fe/c5*1-2;

InChI key

FYOFOKCECDGJBF-UHFFFAOYSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Green Chemistry. This product has been enhanced for catalytic efficiency. Click here for more information.

Application

Chemical Synthesis of Monodisperse Magnetic Nanoparticles
Reactant for:
  • Addition reactions
  • Decomposition via photolysis
  • Preparation of magnetic Fe onion-like fullerene micrometer-sized particles of narrow size distribution via thermal decomposition
  • Preparation of a heptanuclear iron carbonyl cluster used in catalytic hydrosilane reduction of carboxamides

  • Precursor for preparation of Fe nanoparticles for photocatalytic hydrogen evolution under highly basic conditions

pictograms

FlameSkull and crossbones
GHS02,GHS06

signalword

Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Acute Tox. 3 Dermal - Flam. Liq. 2

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

5.0 °F - closed cup

flash_point_c

-15 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 4

1 of 4

Bis(pentamethylcyclopentadienyl)iron(II) 97%

Sigma-Aldrich

378542

Bis(pentamethylcyclopentadienyl)iron(II)

Dioctyl ether 99%

Sigma-Aldrich

249599

Dioctyl ether

Tungsten hexacarbonyl 97%

Sigma-Aldrich

241431

Tungsten hexacarbonyl

Dicarbonylcyclopentadienyl cobalt(I) technical grade

Sigma-Aldrich

245259

Dicarbonylcyclopentadienyl cobalt(I)

Tetsu Mitsumata et al.
The journal of physical chemistry. B, 116(40), 12341-12348 (2012-09-15)
A new class of magnetoelastic gel that demonstrates drastic and reversible changes in storage modulus without using strong magnetic fields was obtained. The magnetic gel consists of carrageenan and carbonyl iron particles. The magnetic gel with a volume fraction of
Caixia Zhan et al.
Dalton transactions (Cambridge, England : 2003), 39(46), 11255-11262 (2010-10-23)
By using "click" chemistry between a diazide and a diiron model complex armed with two alkynyl groups, two polymeric diiron complexes (Poly-Py and Poly-Ph) were prepared. The two polymeric complexes were investigated using infrared spectroscopy, scanning electron microscopy (SEM), transmission
H Ohoyama et al.
The journal of physical chemistry. A, 115(40), 10888-10893 (2011-09-13)
The atomic alignment effect has been studied for the dissociative energy transfer reaction of metal carbonyls (Fe(CO)(5), Ni(CO)(4)) with the oriented Ar ((3)P(2), M(J) = 2). The emission intensity from the excited metal products (Fe*, Ni*) has been measured as
Ioan Silaghi-Dumitrescu et al.
Journal of the American Chemical Society, 130(3), 901-906 (2008-01-01)
Density functional theory studies on a series of Fe2(CO)6(PX)2 derivatives show the tetrahedrane to be the most stable for the alkyl (X = Me, tBu), P-H (X = H), and chloro (X = Cl) derivatives. However, butterfly diradical and planar
R A Toshkova et al.
Journal of ethnopharmacology, 109(3), 394-399 (2006-09-19)
A purified saponin mixture (PSM) from Astragalus corniculatus Bieb. protected significantly hamsters against the experimental Graffi myeloid tumor. The application of PSM increased the survival rates, prolonged mean survival time and the tumor growth was markedly reduced. A purified saponin
View All Related Papers

Articles

Solvothermal Synthesis of Nanoparticles

Solvothermal synthesis is a method for preparing a variety of materials such as metals, semiconductors, ceramics, and polymers.

Chemical Synthesis of Monodisperse Magnetic Nanoparticles

Magnetic nanoparticles have attracted tremendous attention due to their novel properties and their potential applications in magnetic recording, magnetic energy storage and biomedicine.

Recent Progress in Spintronic Materials

Spin-based electronic (spintronic) devices offer significant improvement to the limits of conventional charge-based memory and logic devices which suffer from high power usage, leakage current, performance saturation, and device complexity.

Nanowire Synthesis: From Top-Down to Bottom-Up

The properties of many devices are limited by the intrinsic properties of the materials that compose them.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service