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536040

Sigma-Aldrich

4-4′-Dimethoxy-2-2′-bipyridine

greener alternative

97%

Synonym(s):

4,4′-Dimethoxy-2,2′-bipyridyl, 4,4′-Dimethoxy-2,2′-dipyridyl

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About This Item

Empirical Formula (Hill Notation):
C12H12N2O2
CAS Number:
17217-57-1
Molecular Weight:
216.24
MDL number:
MFCD00233880
UNSPSC Code:
12352100
PubChem Substance ID:
24878130

Quality Level

200

assay

97%

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

mp

168-171 °C (lit.)

greener alternative category

, Aligned

SMILES string

COc1ccnc(c1)-c2cc(OC)ccn2

InChI

1S/C12H12N2O2/c1-15-9-3-5-13-11(7-9)12-8-10(16-2)4-6-14-12/h3-8H,1-2H3

InChI key

IMEVSAIFJKKDAP-UHFFFAOYSA-N

Related Categories

General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalysis. Find details here.

Application

4-4′-Dimethoxy-2-2'-bipyridine may be used as a ligand in the preparation of transition metal complexes.

Ligand for greener oxidation of alcohols under aerobic conditions.

Copper(I)/ABNO-Catalyzed Aerobic Alcohol Oxidation: Alleviating Steric and Electronic Constraints of Cu/TEMPO Catalyst Systems

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

dust mask type N95 (US), Eyeshields, Gloves

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Julie Urgiles et al.
Dalton transactions (Cambridge, England : 2003), 46(41), 14256-14263 (2017-10-11)
Reactions of K
Photochemical isomerization of trans- to cis-[RuCl2(dppb)(4,4'-X2-2,2'-bipy)](X=-H,-NO2,-Me,-COOH,-SMe,-O=SMe,-Cl,-OMe) complexes.
Santiago MO, et al.
Polyhedron, 22(24), 3205-3211 (2003)
Synthesis and characterization of a new family of luminescent cis-(4, 4'-X2-5, 5'-Y2-2, 2'-bipyridine) 2Os (CO) Cl (PF6) complexes (X= NEt2, OMe, Me, H, Cl, Y= H; X= H, Y= Me; X= Y= Me): control of excited-state properties by bipyridyl substituents.
Della CL, et al.
Inorganic Chemistry, 29(15), 2792-2798 (1990)
Efficient osmium sensitizers containing 2,2'-bipyridine-4,4'-bisphosphonic acid ligand.
Zabri H, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 166(1), 99-106 (2004)
Katia M Oliveira et al.
Journal of inorganic biochemistry, 176, 66-76 (2017-09-04)
New Ru(II) complexes with lawsone (law) characterized as trans-[Ru(law)(PPh

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