Skip to Content
MilliporeSigma
All Photos(2)

Documents

550574

Sigma-Aldrich

Methanol-OD

99 atom % D

Synonym(s):

mono-Deuteromethanol, Methan(ol-d), Methyl alcohol-OD

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Linear Formula:
CH3OD
CAS Number:
1455-13-6
Molecular Weight:
33.05
Beilstein/REAXYS Number:
1730948
EC Number:
215-933-0
MDL number:
MFCD00044213
UNSPSC Code:
12142201
PubChem Substance ID:
24879126
NACRES:
NA.21

isotopic purity

99 atom % D

Quality Level

100

assay

≥99.00%

form

liquid

expl. lim.

5.5-36.5 % (lit.)

technique(s)

NMR: suitable

impurities

≤0.0250% water
water

refractive index

n20/D 1.327 (lit.)

bp

65.5 °C (lit.)

mp

-99 °C (lit.)

density

0.813 g/mL at 25 °C (lit.)

mass shift

M+1

SMILES string

[2H]OC

InChI

1S/CH4O/c1-2/h2H,1H3/i2D

InChI key

OKKJLVBELUTLKV-VMNATFBRSA-N

Looking for similar products? Visit Product Comparison Guide

Related Categories

General description

Methanol-OD is a deuterated form of methanol. It is used as a solvent in NMR-based research and analyses.

Application

Methanol-OD can be used as a deuterated solvent to:
  • Perform APPI HDX MS (atmospheric pressure photoionization hydrogen/deuterium exchange mass spectrometry).
  • Synthesis 1,4-butanediol-D6 (1,4-BD-D6)from 1,4-butanediol-D8.

Recommended products

Check out ChemisTwin®, our brand new online portal for identity confirmation and quantification of NMR spectra. Learn more or reach out to us for a free trial.

signalword

Danger

Hazard Classifications

Acute Tox. 3 Dermal - Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Flam. Liq. 2 - STOT SE 1

Storage Class

3 - Flammable liquids

wgk_germany

WGK 2

flash_point_f

51.8 °F - closed cup

flash_point_c

11.0 °C - closed cup

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 5

1 of 5

(Chlorodifluoromethyl)benzene 96%

Sigma-Aldrich

759309

(Chlorodifluoromethyl)benzene

Methanol-d4 ≥99.8 atom % D

Sigma-Aldrich

441384

Methanol-d4

Methanol-d4 ≥99.8 atom % D, contains 1 % (v/v) TMS

Sigma-Aldrich

417653

Methanol-d4

Methanol-d4 reagent grade, ≥99 atom % D, ≥99% (CP)

Sigma-Aldrich

900596

Methanol-d4

Acetic acid-d 99 atom % D

Sigma-Aldrich

151777

Acetic acid-d

High Resolution Fourier Transform Far Infrared Spectroscopy of CH3OD.
Mukhopadhyay I, et al.
Journal of Molecular Spectroscopy, 186(1), 15-21 (1997)
Dehydration of alcohols over alumina. VIII. Ether formation from the deuterated methanols CH3OH, CD3OH, CH3OD, and CD3OD.
Knozinger H, et al.
The Journal of Physical Chemistry, 72(8), 2770-2774 (1968)
The Raman Spectra of the Methyl Alcohols, CH3OH, CH3OD, and CH2DOD.
Halford JO, et al.
J. Chem. Phys. , 5(12), 927-932 (1937)
Photoionization of CH3OH, CD3OH, and CH3OD: Dissociative ionization mechanisms and ionic structures.
Berkowitz J.
J. Chem. Phys., 69(7), 3044-3054 (1978)
Deuterium isotope effect on the solvation dynamics of methanol: CH3OH, CH3OD, CD3OH, and CD3OD.
Shirota H, et al.
The Journal of Physical Chemistry, 100.(35), 14575-14577 (1996)
View All Related Papers

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service