Skip to Content
MilliporeSigma
All Photos(1)

Documents

558788

Sigma-Aldrich

2-Ethynyltoluene

97%

Sign Into View Organizational & Contract Pricing
All Photos(1)

About This Item

Linear Formula:
CH3C6H4C≡CH
CAS Number:
766-47-2
Molecular Weight:
116.16
MDL number:
MFCD03427202
UNSPSC Code:
12352100
PubChem Substance ID:
24879773
NACRES:
NA.22

Quality Level

100

assay

97%

refractive index

n20/D 1.5470 (lit.)

bp

50-60 °C/30 mmHg (lit.)

density

0.922 g/mL at 25 °C (lit.)

SMILES string

Cc1ccccc1C#C

InChI

1S/C9H8/c1-3-9-7-5-4-6-8(9)2/h1,4-7H,2H3

InChI key

MYBSUWNEMXUTAX-UHFFFAOYSA-N

Related Categories

General description

2-Ethynyltoluene undergoes dimerization in the presence of an ionic catalyst.

Application

2-Ethynyltoluene may be used in the synthesis of Ph2N(2-MeC6H4)C=CH2.

pictograms

FlameExclamation mark
GHS02,GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

95.0 °F - closed cup

flash_point_c

35 °C - closed cup

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 4

1 of 4

1-Ethynyl-4-fluorobenzene 99%

Sigma-Aldrich

404330

1-Ethynyl-4-fluorobenzene

2-ethynyl-naphthalene AldrichCPR

Sigma-Aldrich

CDS008002

2-ethynyl-naphthalene

4-tert-Butylphenylacetylene 96%

Sigma-Aldrich

593001

4-tert-Butylphenylacetylene

3-Chloro-1-ethynylbenzene 97%

Sigma-Aldrich

630268

3-Chloro-1-ethynylbenzene

Frustrated Lewis Pair Catalyzed Hydroamination of Terminal Alkynes.
Mahdi T and Stephan DW.
Angewandte Chemie (International Edition in English), 52(47), 12418-12421 (2013)
Scandium, yttrium, and lanthanum benzyl and alkynyl complexes with the N-(2-pyrrolidin-1-ylethyl)-1, 4-diazepan-6-amido ligand: Synthesis, characterization, and Z-selective catalytic linear dimerization of phenylacetylenes.
Ge S, et al.
Organometallics, 28(3), 719-726 (2009)
Yasuhito Suzuki et al.
Forensic science international, 278, 228-239 (2017-08-02)
Various autopsy findings are used for the diagnosis of burning death, including inhalation injury, soot in the respiratory tract, vital reaction, blood carboxyhemoglobin (COHb), and blood cyanide. However, not all findings are necessarily complete, and autopsy diagnosis can be difficult

Articles

New Aromatic Terminal Alkynes

The terminal alkyne functionality has a wide range of applications including most recently the synthesis of spiropyran substituted 2,3-dicyanopyrazines and (±)-asteriscanolide, as well as conversion to enamines using resin-bound 2° amines.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service