567671
Dichlorobis(trimethylphosphine)nickel(II)
97%
Synonym(s):
Bis(trimethylphosphine)nickel dichloride
About This Item
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assay
97%
form
solid
reaction suitability
core: nickel
reagent type: catalyst
mp
194-199 °C (lit.)
λmax
244 nm
SMILES string
Cl[Ni]Cl.CP(C)C.CP(C)C
InChI
1S/2C3H9P.2ClH.Ni/c2*1-4(2)3;;;/h2*1-3H3;2*1H;/q;;;;+2/p-2
InChI key
KYHNNWWCXIOTKC-UHFFFAOYSA-L
Related Categories
Application
- Wenkert arylation of thiophene with aryl Grignard reagents
- Regioselective [2+2+2] cycloaddition of carboryne with alkynes to give benzocarborane compounds
- Kumada-Corriu cross coupling of Grignard reagents
- Borylation of aryl chlorides
- Reductive aldol cyclization-lactonization
- Arylcyanation of alkynes
- Alkynylation of benzonitriles via C-C bond activation
signalword
Warning
hcodes
Hazard Classifications
Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
dust mask type N95 (US), Eyeshields, Gloves
Certificates of Analysis (COA)
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Articles
Nickel transition metal and its complexes can be used as a catalyst in many synthetic transformations, like oxidative addition, C-H activation, reductive elimination, oxidative cyclization, oligomerization, and in cross-coupling reactions.
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