63405
Methyl potassium malonate
≥99.0% (NT)
Synonym(s):
Monomethyl malonate potassium salt, Potassium monomethyl malonate
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About This Item
Linear Formula:
CH3OCOCH2COOK
CAS Number:
Molecular Weight:
156.18
Beilstein/REAXYS Number:
3633585
EC Number:
MDL number:
UNSPSC Code:
12352100
PubChem Substance ID:
NACRES:
NA.22
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Quality Level
assay
≥99.0% (NT)
SMILES string
[K+].COC(=O)CC([O-])=O
InChI
1S/C4H6O4.K/c1-8-4(7)2-3(5)6;/h2H2,1H3,(H,5,6);/q;+1/p-1
InChI key
WWTULTKUWBKVGV-UHFFFAOYSA-M
Related Categories
Application
Methyl potassium malonate can be used in the total synthesis of (±)-vincorine, an akuammiline alkaloid which can find applications in biology. It can also be used to synthesize a key keto proline ester intermediate to prepare acutumine.
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
ppe
Eyeshields, Gloves, type N95 (US)
Certificates of Analysis (COA)
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"The akuammiline alkaloids; origin and synthesis"
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?Classical carbonyl reactivity enables a short synthesis of the core structure of acutumine?
Moreau.JR and Sorensen.JE
Tetrahedron, 63(28), 6446-6453 (2007)
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