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637939

Sigma-Aldrich

1-Bromo-2,4,6-triisopropylbenzene

95%

Synonym(s):

2,4,6-Triisopropylbromobenzene, 2-Bromo-1,3,5-triisopropylbenzene

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About This Item

Empirical Formula (Hill Notation):
C15H23Br
CAS Number:
21524-34-5
Molecular Weight:
283.25
MDL number:
MFCD00051547
UNSPSC Code:
12352100
PubChem Substance ID:
24882896
NACRES:
NA.22

Quality Level

300

assay

95%

refractive index

n20/D 1.523 (lit.)

bp

96-97 °C/0.1 mmHg (lit.)

density

1.118 g/mL at 25 °C (lit.)

SMILES string

CC(C)c1cc(C(C)C)c(Br)c(c1)C(C)C

InChI

1S/C15H23Br/c1-9(2)12-7-13(10(3)4)15(16)14(8-12)11(5)6/h7-11H,1-6H3

InChI key

FUMMYHVKFAHQST-UHFFFAOYSA-N

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Application

1-Bromo-2,4,6-triisopropylbenzene can be used in the synthesis of 1-fluoro-2,4,6-triisopropylbenzene, a fluorine-substituted aromatic building block for agrochemical synthesis and pharmaceutical production. It can also be used in the synthesis of di-2,4,6-triisopropylphenyl diselenide via reaction with metallic selenium in the presence of tertiary-butyl lithium.

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Eyeshields, Gloves, multi-purpose combination respirator cartridge (US)

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"Stereoselective synthesis of (E)-1-iodo-1-selenoalkenes via hydroalumination?iodination of 1-alkynyl selenides"
Balado-Perez S, et al
Tetrahedron Letters, 46(29), 4883-4886 (2005)

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