Skip to Content
MilliporeSigma
All Photos(2)

Documents

663085

Sigma-Aldrich

(5S)-(−)-2,2,3-Trimethyl-5-benzyl-4-imidazolidinone dichloroacetic acid

97%

Synonym(s):

(5S)-2,2,3-Trimethyl-5-phenylmethyl-4-imidazolidinone dichloroacetic acid

Sign Into View Organizational & Contract Pricing
All Photos(2)

About This Item

Empirical Formula (Hill Notation):
C15H20Cl2N2O3
CAS Number:
345358-20-5
Molecular Weight:
347.24
MDL number:
MFCD08276841
UNSPSC Code:
12352005
PubChem Substance ID:
24884183
NACRES:
NA.22

Quality Level

100

assay

97%

mp

122-126 °C

SMILES string

OC(=O)C(Cl)Cl.CN1C(=O)[C@H](Cc2ccccc2)NC1(C)C

InChI

1S/C13H18N2O.C2H2Cl2O2/c1-13(2)14-11(12(16)15(13)3)9-10-7-5-4-6-8-10;3-1(4)2(5)6/h4-8,11,14H,9H2,1-3H3;1H,(H,5,6)/t11-;/m0./s1

InChI key

YZRAPAXOLQHZSE-MERQFXBCSA-N

Related Categories

Application

Utilized in the first example of organocatalytic enantioselective α-fluorination of aldehydes.

Legal Information

U.S. Pat. 6,369,243 and related patents apply. For research purposes only.

pictograms

CorrosionExclamation mark
GHS05,GHS07

signalword

Danger

Hazard Classifications

Eye Dam. 1 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

Already Own This Product?

Find documentation for the products that you have recently purchased in the Document Library.

Visit the Document Library

Customers Also Viewed

Slide 1 of 2

1 of 2

Phenylacetaldehyde ≥90%

Sigma-Aldrich

107395

Phenylacetaldehyde

Dimethyl sulfide anhydrous, ≥99.0%

Sigma-Aldrich

274380

Dimethyl sulfide

Teresa D Beeson et al.
Journal of the American Chemical Society, 127(24), 8826-8828 (2005-06-16)
The first direct enantioselective catalytic alpha-fluorination of aldehydes has been accomplished. The use of enamine catalysis has provided a new organocatalytic strategy for the enantioselective fluorination of aldehydes to generate alpha-fluoro aldehydes, an important chiral synthon for medicinal agent synthesis.

Articles

Macmillan Imidazolidinone Organocatalysts

In collaboration with Materia, Inc., we are pleased to offer six imidazolidinone OrganoCatalysts™.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

Contact Technical Service