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731382

Sigma-Aldrich

(2R,2′R-(+)-[N,N′-Bis(2-pyridylmethyl)]-2,2′-bipyrrolidinebis(acetonitrile)iron(II) hexafluoroantimonate

greener alternative

Synonym(s):

Fe(R,R-PDP), Iron(II) (R,R-(2-({(R)-2-[(R)-1-(pyridin-2-ylmethyl)pyrrolidin-2-yl]pyrrolidin-1-yl}methyl)pyridine)(bis-acetonitrile) hexafluoroantimonate, White-Chen catalyst, [Fe(R,R-PDP)(CH3CN)2](SbF6)2

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About This Item

Empirical Formula (Hill Notation):
C24H32F12FeN6Sb2
CAS Number:
1361315-26-5
Molecular Weight:
931.90
MDL number:
MFCD16038114
UNSPSC Code:
12161600
PubChem Substance ID:
329764650
NACRES:
NA.22

form

powder

Quality Level

100

reaction suitability

core: iron
reagent type: catalyst

greener alternative product characteristics

Catalysis
Learn more about the Principles of Green Chemistry.

sustainability

Greener Alternative Product

mp

215-226 °C

greener alternative category

, Aligned

SMILES string

[Fe++].CC#N.CC#N.F[Sb-](F)(F)(F)(F)F.F[Sb-](F)(F)(F)(F)F.C1C[C@H]([C@H]2CCCN2Cc3ccccn3)N(C1)Cc4ccccn4

InChI

1S/C20H26N4.2C2H3N.12FH.Fe.2Sb/c1-3-11-21-17(7-1)15-23-13-5-9-19(23)20-10-6-14-24(20)16-18-8-2-4-12-22-18;2*1-2-3;;;;;;;;;;;;;;;/h1-4,7-8,11-12,19-20H,5-6,9-10,13-16H2;2*1H3;12*1H;;;/q;;;;;;;;;;;;;;;+2;2*+5/p-12/t19-,20-;;;;;;;;;;;;;;;;;/m1................./s1

InChI key

XUNWHBGEOCZDBX-QSKJABRXSA-B

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General description

We are committed to bringing you Greener Alternative Products, which adhere to one or more of The 12 Principles of Greener Chemistry. This product has been enhanced for catalytic efficiency. Find details here.

Application

Catalyst for greener ketone synthesis by selective C-H oxidation of methylenes.

Combined Effects on Selectivity in Fe-Catalyzed Methylene Oxidation

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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