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756792

Sigma-Aldrich

3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane

97%

Synonym(s):

DAPTA

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About This Item

Empirical Formula (Hill Notation):
C9H16N3O2P
CAS Number:
63249-99-0
Molecular Weight:
229.22
MDL number:
MFCD21608498
UNSPSC Code:
12352005
PubChem Substance ID:
329766617
NACRES:
NA.22

Quality Level

100

assay

97%

form

solid

mp

183 °C (decomposition)

SMILES string

CC(=O)N1CN2CN(CP(C2)C1)C(C)=O

InChI

1S/C9H16N3O2P/c1-8(13)11-3-10-4-12(9(2)14)7-15(5-10)6-11/h3-7H2,1-2H3

InChI key

MYJHMDGWZWBLCK-UHFFFAOYSA-N

Related Categories

Application

3,7-Diacetyl-1,3,7-triaza-5-phosphabicyclo[3.3.1]nonane is a phosphine ligand and acetylized derivative of 1,3,5-triaza-7-phosphaadamantane that can be used:
  • As a ligand in the synthesis of diiron dithiolate complexes of Fe-only hydrogenase to improve the hydro- and protophilicity of the active site.
  • To prepare (η6-arene)-ruthenium(II) complex, which is employed as a catalyst in the reduction of allylic alcohols.
  • As a ligand in the synthesis of water-soluble cis- and trans-Pt(II) and Pd(II) metal complexes.

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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