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791105

Sigma-Aldrich

Zinc chloromethanesulfinate

95% (H-NMR)

Synonym(s):

Baran MCMS Reagent

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About This Item

Empirical Formula (Hill Notation):
C2H4Cl2O4S2Zn
CAS Number:
Molecular Weight:
292.48
MDL number:
UNSPSC Code:
12352101
PubChem Substance ID:
NACRES:
NA.22

Quality Level

assay

95% (H-NMR)

form

solid

reaction suitability

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

reagent type: diversification reagent

mp

190-195 °C

storage temp.

2-8°C

SMILES string

ClCS(O[Zn]OS(CCl)=O)=O

InChI

1S/2CH3ClO2S.Zn/c2*2-1-5(3)4;/h2*1H2,(H,3,4);/q;;+2/p-2

InChI key

HEKATMPPXNXYJU-UHFFFAOYSA-L

Application

Zinc chloromethanesulfinate (MCMS) is part of a zinc sulfinate toolbox developed by Phil Baran for the simple and rapid diversification of heterocycles.1

Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles

Learn More at the Professor and Product Portal of Professor Phil S. Baran.

pictograms

Exclamation mark

signalword

Warning

hcodes

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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Journal of the American Chemical Society
O'Hara,F.; et. al.
Journal of the American Chemical Society, 135, 12122-12134 null
Practical and Innate Carbon-Hydrogen Functionalization of Heterocycles
Fujiwara, Y.; et al.
Nature, 492, 95-100 (2013)

Articles

The synthesis of heteroaromatic and aromatic compounds is at the heart of the chemical industry. The ever-growing demand for new chemical entities, coupled with dwindling resources and time constraints allotted to any given research project, a rapid way to diversify (hetero)aromatic scaffolds is needed.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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