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798711

Sigma-Aldrich

(R)-Xyl-SDP(O)

Synonym(s):

(R)-Xyl-SDP Oxide, [(1R)-7′-[Bis(3,5-dimethylphenyl)phosphino]-2,2′,3,3′-tetrahydro-1,1′-spirobi[1H-inden]-7-yl]bis(3,5-dimethylphenyl)phosphine oxide

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About This Item

Empirical Formula (Hill Notation):
C49H50OP2
CAS Number:
Molecular Weight:
716.87
UNSPSC Code:
12352000
PubChem Substance ID:
NACRES:
NA.22

assay

≥95%

Quality Level

form

solid

storage temp.

2-8°C

SMILES string

CC1=CC(C)=CC(P(C2=CC(C)=CC(C)=C2)(C3=CC=CC4=C3[C@]5(CCC6=C5C(P(C7=CC(C)=CC(C)=C7)C8=CC(C)=CC(C)=C8)=CC=C6)CC4)=O)=C1

InChI

1S/C49H50OP2/c1-31-19-32(2)24-41(23-31)51(42-25-33(3)20-34(4)26-42)45-13-9-11-39-15-17-49(47(39)45)18-16-40-12-10-14-46(48(40)49)52(50,43-27-35(5)21-36(6)28-43)44-29-37(7)22-38(8)30-44/h9-14,19-30H,15-18H2,1-8H3/t49-/m1/s1

InChI key

ZAQVAUFRFBAVHF-ANFMRNGASA-N

Related Categories

Application

Chiral ligand introduced in collaboration with Prof. Steve Zhou and coworkers, has shown utility in asymmetric Heck reactions for both intra and intermolecular C-C bond formation with various triflates and halides.

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable


Certificates of Analysis (COA)

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Related Content

Prof. Zhou's research group in Singapore is mainly interested in developing late metal-catalyzed reactions for fundamental C-C bond formation. Recently, they have solved several problems in palladium catalysis.

Our team of scientists has experience in all areas of research including Life Science, Material Science, Chemical Synthesis, Chromatography, Analytical and many others.

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