900920
Bis[[diisopropylphosphino]methyl]-4-methyl-pyridine bis(pivaloyloxy)cobalt
95%
Synonym(s):
Chirik cobalt borylation catalyst, JENNY cobalt borylation catalyst, JennyCat
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About This Item
Empirical Formula (Hill Notation):
C30H55CoNO4P2
CAS Number:
Molecular Weight:
614.64
UNSPSC Code:
12161600
NACRES:
NA.22
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Quality Level
assay
95%
form
powder
reaction suitability
core: cobalt
reagent type: catalyst
mp
>300 °C
SMILES string
CC1=CC(CP(C(C)C)C(C)C)=NC(CP(C(C)C)C(C)C)=C1.O=C(C(C)(C)C)O[Co]OC(C(C)(C)C)=O
Related Categories
Application
Bis[[diisopropylphosphino]methyl]-4-methyl-pyridine bis(pivaloyloxy)cobalt also known as JennyCat is developed in the laboratory of Paul Chirik is an effective cobalt precatalyst for the borylation of aromatic compounds, including diverse heteroarenes, pyridine derivatives, and fluoroarenes.
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificates of Analysis (COA)
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Jennifer V Obligacion et al.
Journal of the American Chemical Society, 139(7), 2825-2832 (2017-02-01)
Cobalt catalysts with electronically enhanced site selectivity have been developed, as evidenced by the high ortho-to-fluorine selectivity observed in the C(sp
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