904848
2-Chloro-1,3-bis(2,6-diisopropylphenyl)imidazolium chloride
≥95%
Synonym(s):
1,3-Bis(2,6-di-i-propylphenyl)-2-chloroimidazolium chloride, Chloroimidazolium chloride
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All Photos(3)
About This Item
Empirical Formula (Hill Notation):
C27H36Cl2N2
CAS Number:
Molecular Weight:
459.49
MDL number:
UNSPSC Code:
12352101
NACRES:
NA.22
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assay
≥95%
form
powder
InChI
1S/C27H36ClN2.ClH/c1-17(2)21-11-9-12-22(18(3)4)25(21)29-15-16-30(27(29)28)26-23(19(5)6)13-10-14-24(26)20(7)8;/h9-20H,1-8H3;1H/q+1;/p-1
InChI key
JDMACANGISWEGX-UHFFFAOYSA-M
Related Categories
Application
This chloroimidazolium chloride is used in the deoxyfluorination of phenols. Recently, the Ritter lab used it in conjunction with 902314 and 906794 to incorporate the [18F]fluoride radiolabel site specifically into polypeptides for use with positron emission tomography (PET) imaging in the study of various biological applications.
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related product
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
Certificates of Analysis (COA)
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Jisu Back et al.
Journal of the American Chemical Society, 139(43), 15300-15303 (2017-10-19)
Notwithstanding the notable progress in the synthesis of N-heterocyclic carbene-stabilized radicals, aminyl radicals, supported by NHCs or otherwise, have been scarcely studied due to synthetic challenges. Triazenyl radical is a particular form of aminyl radical that contains three adjacent nitrogen
Teppei Fujimoto et al.
Organic letters, 17(3), 544-547 (2015-01-27)
A practical deoxyfluorination with novel deoxyfluorinating reagent PhenoFluorMix, a mixture of N,N'-1,3-bis(2,6-diisopropylphenyl)chloroimidazolium chloride and CsF, is presented. PhenoFluorMix overcomes the challenges associated with hydrolysis of PhenoFluor. PhenoFluorMix does not hydrolyze, is readily available on decagram scale, and is storable in
Nathaniel W Goldberg et al.
Organic letters, 18(23), 6102-6104 (2016-12-10)
A practical, high-yielding method for the deoxyfluorination of alcohols is presented using AlkylFluor, a novel salt analogue of PhenoFluor. AlkylFluor is readily prepared on multigram scale and is stable to long-term storage in air and exposure to water. The practicality
Corrigendum: Concerted nucleophilic aromatic substitution with 19F- and 18F.
Constanze N Neumann et al.
Nature, 538(7624), 274-274 (2016-08-04)
Martin G Strebl et al.
ACS central science, 3(9), 1006-1014 (2017-10-06)
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