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908193

Sigma-Aldrich

3CzClIPN

Synonym(s):

2,4,6-Tri(9H-carbazol-9-yl)-5-chloroisophthalonitrile

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About This Item

Empirical Formula (Hill Notation):
C44H24ClN5
CAS Number:
1469704-61-7
Molecular Weight:
658.15
UNSPSC Code:
12352101

form

powder or crystals

reaction suitability

reaction type: Photocatalysis
reagent type: catalyst

mp

>300 °C

Related Categories

Application

3CzClIPN is cyanoarene-based donor-acceptor photocatalyst developed by the Zeitler group. While this catalyst has a balanced redox profile, allowing for its use in a variety of transformations, it stands out as the most oxidizing catalyst of the family.

Product can be used with our line of photoreactors: Including Penn PhD (Z744035) & SynLED 2.0 (Z744080)

Other Notes

A Toolbox Approach To Construct Broadly Applicable Metal-Free Catalysts for Photoredox Chemistry: Deliberate Tuning of Redox Potentials and Importance of Halogens in Donor-Acceptor Cyanoarenes

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Storage Class

11 - Combustible Solids

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

Certificates of Analysis (COA)

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Elisabeth Speckmeier et al.
Journal of the American Chemical Society, 140(45), 15353-15365 (2018-10-03)
The targeted choice of specific photocatalysts has been shown to play a critical role for the successful realization of challenging photoredox catalytic transformations. Herein, we demonstrate the successful implementation of a rational design strategy for a series of deliberate structural

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