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1.06044

Supelco

Dichloromethane

for liquid chromatography LiChrosolv®

Synonym(s):

DCM, Methylene chloride, Methylene dichloride, Methylene chloride

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About This Item

Empirical Formula (Hill Notation):
CH2Cl2
CAS Number:
Molecular Weight:
84.93
Beilstein/REAXYS Number:
1730800
MDL number:
UNSPSC Code:
12191502
EC Index Number:
200-838-9
NACRES:
NA.03

vapor density

2.9 (vs air)

Quality Level

vapor pressure

24.45 psi ( 55 °C)
6.83 psi ( 20 °C)

product line

LiChrosolv®

grade

isocratic

assay

≥99.9% (GC)

form

liquid

autoignition temp.

1223 °F
605 °C (DIN 51794)

potency

1600 mg/kg LD50, oral (Rat)
>2000 mg/kg LD50, skin (Rat)

contains

2-methyl-2-butene as stabilizer

expl. lim.

22 %

technique(s)

HPLC: suitable

impurities

≤0.0002 meq/g Acidity
≤0.0002 meq/g Alkalinity
≤0.01% Water

evapn. residue

≤5.0 mg/L

transmittance

240 nm, ≥70%
245 nm, ≥90%
260 nm, ≥99%

refractive index

n20/D 1.424 (lit.)

pH

7 (20 °C)

bp

39.8-40 °C (lit.)

mp

-95 °C
−95 °C (lit.)

solubility

20 g/L

density

1.325 g/mL at 25 °C (lit.)

storage temp.

2-30°C

SMILES string

ClCCl

InChI

1S/CH2Cl2/c2-1-3/h1H2

InChI key

YMWUJEATGCHHMB-UHFFFAOYSA-N

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General description

LiChrosolv® solvents exhibit high degree of UV transmittance, low particle count, low acidity and alkalinity and low evaporation residue level. This makes them ideal for reproducible separations.
We are committed to bringing you Greener Alternative Products which adhere to one or more of The 12 Principles of Greener Chemistry. This solution of Ethyl acetate/Ethanol is a greener alternative to dichloromethane for chromatographic purification and thus has been enhanced for Safer Solvents and Auxiliaries. Click here for more information.

Application

Intended for HPLC and UHPLC-MS applications.

Features and Benefits

  • suitability tested and specified for UHPLC-MS and UHPLC-UV: for analytical flexibility
  • specified quality in positive and negative in positive and negative electrospray ionization (ESI) and atmospheric-pressure chemical ionization-mass spectrometry (APCI-MS) for lowest detection limits and confidence in analyses for all important MS modes (test 1)
    —ESI/APCI (+) < 2 ppb
    —ESI/APCI (-) < 10 ppb
  • lowest impurity profile: for interference-free baselines (test 2)
  • microfiltered through 0.2 μm filter (test 3) to provide:
    —a long lifespan to filters and mechanical parts of HPLC systems
    —reduced risk of column clogging
  • packed in borosilicate glass bottles for minimum metal ion contaminations
  • lowest levels of trace metal impurities for a minimum metal ion adduct formation
    —< 5ppb
  • lowest level of polyethylene glycol (PEG) impurities in UHPLC-MS solvent lineup (PEG S/N signal-to-noise-ratio < 50)

Preparation Note

Product filtered through a 0.2 μm filter

Analysis Note

Purity (GC): ≥ 99.9 %
Identity (IR): conforms
Acidity: ≤ 0.0002 meq/g
Alkalinity: ≤ 0.0002 meq/g
Transmission (at 240 nm): ≥ 70 %
Transmission (at 245 nm): ≥ 90 %
Transmission (from 260 nm): ≥ 99 %
Evaporation residue: ≤ 5.0 mg/l
Water: ≤ 0.01 %
The product is stabilized with 2-Methyl-2-buten.
Filtered by 0.2 µm filter

Other Notes

Explore various lab safety accessories and equipment for safe handling of solvents to increase your safety level from the first usage.

Legal Information

LICHROSOLV is a registered trademark of Merck KGaA, Darmstadt, Germany

pictograms

Health hazardExclamation mark

signalword

Warning

Hazard Classifications

Carc. 2 - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Central nervous system

wgk_germany

WGK 2

flash_point_f

does not flash

flash_point_c

does not flash


Certificates of Analysis (COA)

Search for Certificates of Analysis (COA) by entering the products Lot/Batch Number. Lot and Batch Numbers can be found on a product’s label following the words ‘Lot’ or ‘Batch’.

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