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06914

Supelco

Thiophene

analytical standard

Synonym(s):

Thiofuran, Thiole

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About This Item

Empirical Formula (Hill Notation):
C4H4S
CAS Number:
110-02-1
Molecular Weight:
84.14
Beilstein/REAXYS Number:
103222
EC Number:
203-729-4
MDL number:
MFCD00005413
UNSPSC Code:
41116107
PubChem Substance ID:
329748301
NACRES:
NA.24

grade

analytical standard

Quality Level

100

vapor density

2.9 (vs air)

vapor pressure

40 mmHg ( 12.5 °C)

assay

≥99.5% (GC)

autoignition temp.

743 °F

shelf life

limited shelf life, expiry date on the label

expl. lim.

12.5 %

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

impurities

~0.2% benzene

refractive index

n20/D 1.529 (lit.)
n20/D 1.529

bp

84 °C (lit.)

mp

−38 °C (lit.)

density

1.051 g/mL at 25 °C (lit.)

application(s)

environmental

format

neat

SMILES string

c1ccsc1

InChI

1S/C4H4S/c1-2-4-5-3-1/h1-4H

InChI key

YTPLMLYBLZKORZ-UHFFFAOYSA-N

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General description

Thiophene belongs to the class of polycyclic aromatic sulfur heterocycles, which are carcinogenic compounds found in crude oil. Thiopenes are widely used as building blocks in many agrochemicals, pharmaceuticals, and material science.

Application

Thiophene may be used as an analytical reference standard for the quantification of the analyte in diesel oil and crude oil using two-dimensional gas chromatography with sulfur chemiluminescence detection.

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Chronic 3 - Carc. 1A - Eye Irrit. 2 - Flam. Liq. 2 - Muta. 1B

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

15.8 °F

flash_point_c

-9 °C

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCB9369
BCBT9350
BCBP5387V
BCBK5793V
BCBF1107V

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Analysis of sulfur?containing compounds in crude oils by comprehensive two?dimensional gas chromatography with sulfur chemiluminescence detection
Hua R, et al.
Journal of Separation Science, 27(9), 691-698 (2004)
Determination of sulfur-containing compounds in diesel oils by comprehensive two-dimensional gas chromatography with a sulfur chemiluminescence detector
Hua R, et al.
Journal of Chromatography A, 1019(1-2), 101-109 (2003)
Isabella Salzer et al.
Pflugers Archiv : European journal of physiology, 466(12), 2289-2303 (2014-03-29)
The slow cholinergic transmission in autonomic ganglia is known to be mediated by an inhibition of Kv7 channels via M1 muscarinic acetylcholine receptors. However, in the present experiments using primary cultures of rat superior cervical ganglion neurons, the extent of
Joachim Morrens et al.
Neuron, 106(1), 142-153 (2020-02-07)
Dopamine neurons mediate the association of conditioned stimuli (CS) with reward (unconditioned stimuli, US) by signaling the discrepancy between predicted and actual reward during the US. Some theoretical models suggest that learning is also influenced by the salience or associability
Brian Capozzi et al.
Journal of the American Chemical Society, 136(29), 10486-10492 (2014-07-09)
We have measured the single-molecule conductance of a family of oligothiophenes comprising 1-6 thiophene moieties terminated with methyl-sulfide linkers using the scanning tunneling microscope-based break-junction technique. We find an anomalous behavior: the peak of the conductance histogram distribution does not
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