240877
p-Toluenesulfonyl chloride
ReagentPlus®, ≥99%
Synonym(s):
TsCl, Tosyl chloride
About This Item
Recommended Products
vapor pressure
1 mmHg ( 88 °C)
Quality Level
product line
ReagentPlus®
assay
≥99%
form
solid
bp
134 °C/10 mmHg (lit.)
mp
65-69 °C (lit.)
solubility
benzene: freely soluble(lit.)
chloroform: freely soluble(lit.)
ethanol: freely soluble(lit.)
water: insoluble(lit.)
SMILES string
Cc1ccc(cc1)S(Cl)(=O)=O
InChI
1S/C7H7ClO2S/c1-6-2-4-7(5-3-6)11(8,9)10/h2-5H,1H3
InChI key
YYROPELSRYBVMQ-UHFFFAOYSA-N
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General description
Application
- In combination with N-methylimidazole for the esterification or thioesterification of carboxylic acids and alcohols or thiols.
- As an additive to enhance the yield of symmetrical biaryls via palladium chloride catalyzed homo-coupling of arylboronic acids in the absence of ligands.
- As a positive chlorine source for the ?-chlorination of ketones.
- Solvent-free tosylation of alcohols and phenols in the presence of heterodoxy acids.
- As an activator for reaction between 2-alkynylbenzaldoxime and phenols to form 1-aroxyisoquinolines in the presence of silver triflate.
- As a catalyst for the solvent-free preparation of symmetrical bis(benzhydryl)ethers from benzhydrols.
Legal Information
signalword
Danger
Hazard Classifications
Eye Dam. 1 - Met. Corr. 1 - Skin Irrit. 2 - Skin Sens. 1
Storage Class
8B - Non-combustible, corrosive hazardous materials
wgk_germany
WGK 1
flash_point_f
262.4 °F
flash_point_c
128 °C
ppe
Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges
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