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Sigma-Aldrich

Benzophenone imine

95%

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About This Item

Linear Formula:
(C6H5)2C=NH
CAS Number:
1013-88-3
Molecular Weight:
181.23
Beilstein/REAXYS Number:
1100371
MDL number:
MFCD00001760
UNSPSC Code:
12171500
PubChem Substance ID:
24857673
NACRES:
NA.47

Quality Level

100

assay

95%

form

liquid

refractive index

n20/D 1.618 (lit.)

bp

151-153 °C/10 mmHg (lit.)

density

1.08 g/mL at 25 °C (lit.)

application(s)

diagnostic assay manufacturing
hematology
histology

storage temp.

room temp

SMILES string

N=C(c1ccccc1)c2ccccc2

InChI

1S/C13H11N/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10,14H

InChI key

SXZIXHOMFPUIRK-UHFFFAOYSA-N

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General description

Benzophenone imine plays a vital role as an ammonia surrogate. It is primarily used as ammonia equivalents for the selective formation of protected primary amines. Benzophenone imine is useful as a synthetic intermediate, especially for the synthesis of glycine Schiff base.

Application

Benzophenone imine is useful for the preparation of nitrile yield dimers.

pictograms

Exclamation mark
GHS07

signalword

Warning

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

target_organs

Respiratory system

wgk_germany

WGK 3

flash_point_f

228.2 °F

flash_point_c

109 °C

ppe

Eyeshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
STBH3217
STBH3025
STBG8571
STBG8254
STBF4865V

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Suzanne Fergus et al.
The Journal of organic chemistry, 69(14), 4663-4669 (2004-07-03)
A series of novel hexaaryl diazatrienes 5 ("nitrile ylide dimers") were synthesized directly from the corresponding diaryl ketimines 12 and dichlorotoluenes 13 in a facile one-pot synthesis. The carbene character of the nitrile ylides was investigated by varying the substituents

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