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Abamectin

PESTANAL®, analytical standard

Synonym(s):

Avermectin B1

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About This Item

CAS Number:
71751-41-2
MDL number:
MFCD01769550
UNSPSC Code:
41116107
PubChem Substance ID:
329753906
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

−20°C

SMILES string

CCC(C)C1O[C@@]2(C[C@@H]3CC(C\C=C(C)\[C@@H](O[C@H]4C[C@H](OC)[C@@H](O[C@H]5C[C@H](OC)[C@@H](O)[C@H](C)O5)[C@H](C)O4)[C@@H](C)\C=C\C=C6/COC7[C@H](O)C(C)=CC(C(=O)O3)[C@]67O)O2)C=C[C@@H]1C

InChI

1S/C48H72O14/c1-11-25(2)43-28(5)17-18-47(62-43)23-34-20-33(61-47)16-15-27(4)42(26(3)13-12-14-32-24-55-45-40(49)29(6)19-35(46(51)58-34)48(32,45)52)59-39-22-37(54-10)44(31(8)57-39)60-38-21-36(53-9)41(50)30(7)56-38/h12-15,17-19,25-26,28,30-31,33-45,49-50,52H,11,16,20-24H2,1-10H3/b13-12+,27-15+,32-14+/t25-,26-,28-,30-,31-,33+,34-,35?,36-,37-,38-,39-,40+,41-,42-,43+,44-,45+,47+,48+/m0/s1

InChI key

RRZXIRBKKLTSOM-RDKIRRGNSA-N

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General description

Abamectin (MK-0936) belongs to avermectin family. This family have a macrocycle as backbone with a spiroketal unit, a hexahydrobenzofuran unit and disaccharide substitute in general. MK-0936 is a natural fermenting product which can be produced by Streptomyces avermitilis.

Application

Abamectin has been used as standard in liquid chromatography–electrospray tandem mass spectrometry LC–ESI-MS–MS method for determination of abamectin residues in orange samples.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

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Danger

Hazard Classifications

Acute Tox. 1 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Repr. 2 - STOT RE 1

Storage Class

6.1A - Combustible, acute toxic Cat. 1 and 2 / very toxic hazardous materials

wgk_germany

WGK 3

flash_point_f

Not applicable

flash_point_c

Not applicable

ppe

Eyeshields, Faceshields, Gloves, type N95 (US)

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Certificates of Analysis (COA)

Lot/Batch Number
BCCJ9661
BCCD7221
BCCC5853
BCBZ3693
BCBX6101

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Determination of abamectin and azadirachtin residues in orange samples by liquid chromatography?electrospray tandem mass spectrometry.
Pozo, O. J., et al.
Journal of Chromatography A, 992.1, 133-140 (2003)
Xiaojie Liu et al.
Frontiers in plant science, 8, 903-903 (2017-06-15)
The high structural diversity of plant metabolites suggests that interactions among them should be common. We investigated the effects of single metabolites and combinations of plant metabolites on insect herbivores. In particular we studied the interacting effects of pyrrolizidine alkaloid
Antonio Biondi et al.
Chemosphere, 87(7), 803-812 (2012-02-22)
The generalist predator Orius laevigatus (Fieber) (Hemiptera: Anthocoridae) is a key natural enemy of various arthropods in agricultural and natural ecosystems. Releases of this predator are frequently carried out, and it is included in the Integrated Pest Management (IPM) programs
Rajarshi Ghosh et al.
Science (New York, N.Y.), 335(6068), 574-578 (2012-02-04)
Resistance of nematodes to anthelmintics such as avermectins has emerged as a major global health and agricultural problem, but genes conferring natural resistance to avermectins are unknown. We show that a naturally occurring four-amino-acid deletion in the ligand-binding domain of
Andréa Novelli et al.
Chemosphere, 86(1), 36-40 (2011-10-01)
Abamectin is used as an acaricide and insecticide for fruits, vegetables and ornamental plants, as well as a parasiticide for animals. One of the major problems of applying pesticides to crops is the likelihood of contaminating aquatic ecosystems by drift
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