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Supelco

Pirimiphos-methyl

PESTANAL®, analytical standard

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About This Item

Empirical Formula (Hill Notation):
C11H20N3O3PS
CAS Number:
29232-93-7
Molecular Weight:
305.33
Beilstein/REAXYS Number:
755726
EC Number:
249-528-5
MDL number:
MFCD00055366
UNSPSC Code:
41116107
PubChem Substance ID:
329753990
NACRES:
NA.24

grade

analytical standard

Quality Level

100

product line

PESTANAL®

shelf life

limited shelf life, expiry date on the label

technique(s)

HPLC: suitable
gas chromatography (GC): suitable

application(s)

agriculture
environmental

format

neat

storage temp.

2-8°C

SMILES string

CCN(CC)c1nc(C)cc(OP(=S)(OC)OC)n1

InChI

1S/C11H20N3O3PS/c1-6-14(7-2)11-12-9(3)8-10(13-11)17-18(19,15-4)16-5/h8H,6-7H2,1-5H3

InChI key

QHOQHJPRIBSPCY-UHFFFAOYSA-N

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General description

Pirimiphos-methyl (PMM) is an organophosphorous pesticide.

Application

PMM may have been used as reference standard for identification of possible intermediate products formed during photocatalytic degradation of PMM using different chromatographic methods, like GC, HPLC, GC-MS, TOC and LC-MS.
Refer to the product′s Certificate of Analysis for more information on a suitable instrument technique. Contact Technical Service for further support.

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Legal Information

PESTANAL is a registered trademark of Merck KGaA, Darmstadt, Germany

signalword

Danger

Hazard Classifications

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - STOT RE 1 - STOT SE 1

target_organs

Nervous system

Storage Class

6.1C - Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

wgk_germany

WGK 3

ppe

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Certificates of Analysis (COA)

Lot/Batch Number
BCCF9905
BCBT5775
SZBC010XV
SZBB103XV
SZE7151X

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Photocatalytic degradation of pesticide pirimiphos-methyl: Determination of the reaction pathway and identification of intermediate products by various analytical methods.
Herrmann, Jean Marie, et al.
Catalysis Today, 54.2, 353-367 (1999)
Luigi Lucini et al.
Journal of environmental science and health. Part. B, Pesticides, food contaminants, and agricultural wastes, 46(6), 518-524 (2011-07-06)
The aim of this work was to comparatively assess the persistence of pirimiphos methyl residues in cereals and in their milling fractions after spray application in post harvest. An analytical method, based on a slightly modified QuEChERS extraction followed by
Ferdinand Ngoula et al.
African health sciences, 7(1), 3-9 (2007-07-03)
Organophosphate insecticides represent one of the most widely used classes of pesticides with high potential for human exposure in both rural and residential environments. In the present study, we investigated the effects of pirimiphos-methyl (0, 2-diethylamino-6-methylpirimidin-4-yl O, O-dimethyl phosphorothioate), an
Michele Del Carlo et al.
Analytical and bioanalytical chemistry, 381(7), 1367-1372 (2005-03-05)
An electrochemical assay used for detecting acetylcholinesterase (AChE) inhibitors has been optimised to detect pirimiphos-methyl in durum wheat. Pirimiphos-methyl is a phosphothionate insecticide and so it needs to be transformed into the corresponding oxo form to act as an effective
M O Lawal et al.
Pakistan journal of biological sciences : PJBS, 13(8), 405-408 (2010-09-15)
Pirimiphos-methyl is a broad spectrum organophosphate insecticide and potential toxic pollutant in aquatic ecosystems. The acute toxicity of Pirimiphos-methyl (Actellic) was investigated using Guppy (Poecilia reticulata) in a 96 h static renewal laboratory bioassay. Based on probit analysis the LC50
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